The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Hence the admixture of the products of combustion with an
explosive mixture prevents the combustion of the remaining
mass, although capable of burning. The admixture of carbonic
anhydride prevents carbonic oxide from burning. The presence of
any other foreign gas interferes in the same manner. This shows
that every portion of a flame must contain combustible, burning,
and already burnt substances--_i.e._ oxygen, carbon, carbonic
oxide, hydrogen, hydrocarbons, carbonic anhydride, and water.
Consequently, _it is impossible to attain instantaneous complete
combustion_, and this is one of the reasons of the phenomenon
of flame. A certain space is required, and the temperature must
be unequal in different parts of it. In this space different
quantities of the component parts are successively subjected
to combustion, or are cooled under the influence of adjacent
objects, and combustion only ends where the flame ends. If
the combustion could be concentrated at one spot, then the
temperature would be incomparably higher than it is under the
actual circumstances.
The various regions of the flame have formed the frequent
subject of experimental research, and the experiments conducted
by Smithells and Ingle (1892) are particularly instructive;
they show that the reducing (interior) and oxidising (exterior)
portions of the flame of a burning gas may be divided by taking a
Bunsen burner and surrounding the flame of the gas burnt in it,
by another wider tube (without the access of air to the annular
space or allowing only a small current of air to pass), when
a gaseous mixture, containing oxide of carbon and capable of
further combustion, will issue from this enveloping tube, so that
a second flame, corresponding to the exterior (oxidising) portion
of an ordinary flame, may be obtained above the enveloping tube.
This division of the flame into two portions is particularly
clear when cyanogen C_{2}N_{2} is burnt, because the interior
portion (where CO is chiefly formed according to the equation
C_{2}N_{2} + O_{2} = 2CO + N_{2}, but a portion of the nitrogen
is oxidised) is of a rose colour, while the exterior portion
(where the CO burns into CO_{2} at the expense of a fresh
quantity of oxygen and of the oxides of nitrogen proceeding from
the interior portions) is of a bluish-grey colour.
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