The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
The combination of various substances with oxygen may not present
any signs of combustion--that is, the temperature may rise but
inconsiderably. This may either proceed from the fact that the
reaction of the substance (for example, tin, mercury, lead at a
high temperature, or a mixture of pyrogallol with caustic potash at
the ordinary temperature) evolves but little heat, or that the heat
evolved is transmitted to good conductors of heat, like metals, or
that the combination with oxygen takes place so slowly that the heat
evolved succeeds in passing to the surrounding objects. Combustion
is only a particular, intense, and evident case of combination with
oxygen. Respiration is also an act of combination with oxygen; it
also serves, like combustion, for the development of heat by those
chemical processes which accompany it (the transformation of oxygen into
carbonic anhydride). Lavoisier enunciated this in the lucid expression,
'respiration is slow combustion.'
Reactions involving slow combination of substances with oxygen are
termed _oxidations_. Combination of this kind (and also combustion)
often results in the formation of acid substances, and hence the name
_oxygen_ (_Sauerstoff_). Combustion is only rapid oxidation. Phosphorus,
iron, and wine may be taken as examples of substances which slowly
oxidise in air at the ordinary temperature. If such a substance be
left in contact with a definite volume of air or oxygen, it absorbs
the oxygen little by little, as may be seen by the decrease in volume
of the gas. This slow oxidation is not often accompanied by a sensible
evolution of heat; an evolution of heat really does occur, only it
is not apparent to our senses owing to the small rise in temperature
which takes place; this is owing to the slow rate of the reaction and
to the transmission of the heat formed as radiant heat, &c. Thus, in
the oxidation of wine and its transformation into vinegar by the usual
method of preparation of the latter, the heat evolved cannot be observed
because it extends over several weeks, but in the so-called rapid
process of the manufacture of vinegar, when a large quantity of wine is
comparatively rapidly oxidised, the evolution of heat is quite apparent.
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