The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[49] It must be remarked that certain elements form oxides of all three
kinds--_i.e._ indifferent, basic, and acid; for example,
manganese forms manganous oxide, manganic oxide, peroxide of
manganese, red oxide of manganese, and manganic anhydride,
although some of them are not known in a free state but only
in combination. The basic oxides contain less oxygen than the
peroxides, and the peroxides less than the acid anhydrides.
Thus they must be placed in the following general normal
order with respect to the amount of oxygen entering into
their composition--(1) basic oxides, suboxides, and oxides;
(2) peroxides; (3) acid anhydrides. The majority of elements,
however, do not give all three kinds of oxides, some giving only
one degree of oxidation. It must further be remarked that there
are oxides formed by the combination of acid anhydrides with
basic oxides, or, in general, of oxides with oxides. For every
oxide having a higher and a lower degree of oxidation, it might
be said that the intermediate oxide was formed by the combination
of the higher with the lower oxide. But this is not true in all
cases--for instance, when the oxide under consideration forms
a whole series of independent compounds--for oxides which are
really formed by the combination of two other oxides do not give
such independent compounds, but in many cases decompose into the
higher and lower oxides.
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