The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
colourless in an acid, and red in an alkaline, solution. Cyanine
is also colourless in the presence of acids, and gives a blue
coloration with alkalis. Methyl-orange (yellow in an aqueous
solution) is not altered by alkalis but becomes pink with acids
(weak acids have no action), &c. These are very sensitive tests.
Their behaviour in respect to various acids, alkalis, and salts
sometimes give the means of distinguishing substances from each
other.
Basic oxides, in combining with water, form hydrates, of which, however,
very few are soluble in water. Those which are soluble in water have
an alkaline taste like that of soap or of water in which wood ashes
have been boiled, and are called _alkalis_. Further, alkalis have the
property of restoring the blue colour to litmus which has been reddened
by the action of acids. The hydrates of the oxides of sodium and
potassium, NaHO and KHO, are examples of basic hydrates easily soluble
in water. They are true alkalis, and are termed _caustic_, because they
act very powerfully on the skin of animals and plants. Thus NaHO is
called 'caustic' soda.
The saline oxides are capable of combining together and with water.
Water itself is an oxide, and not an indifferent one, for it can, as we
have seen, combine with basic and acid oxides; it is a representative
of a whole series of saline oxides, _intermediate oxides_, capable of
combining with both basic and acid oxides. There are many such oxides,
which, like water, combine with basic and acid anhydrides--for instance,
the oxides of aluminium and tin, &c. From this it may be concluded that
all oxides might be placed, in respect to their capacity for combining
with one another, in one uninterrupted series, at one extremity of which
would stand those oxides which do not combine with the bases--that
is, the alkalis--while at the other end would be the acid oxides, and
in the interval those oxides which combine with one another and with
both the acid and basic oxides. The further apart the members of this
series are, the more stable are the compounds they form together, the
more energetically do they act on each other, the greater the quantity
of heat evolved in their reaction, and the more marked is their saline
chemical character.
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