The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
We said above that basic and acid oxides combine together, but rarely
react on each other; this depends on the fact that the majority of them
are solids or gases--that is, they occur in the state least prone
to chemical reaction. The gaseo-elastic state is with difficulty
destroyed, because it necessitates overcoming the elasticity proper
to the gaseous particles. The solid state is characterised by the
immobility of its particles; whilst chemical action requires contact,
and hence a displacement and mobility. If solid oxides be heated, and
especially if they be melted, then reaction proceeds with great ease.
But such a change of state rarely occurs in nature or in practice.
Only in a few furnace processes is this the case. For example; in the
manufacture of glass, the oxides contained in it combine together in
a molten state. But when oxides combine with water, and especially
when they form hydrates soluble in water, then the mobility of their
particles increases to a considerable extent, and their reaction
is greatly facilitated. Reaction then takes place at the ordinary
temperature--easily and rapidly; so that this kind of reaction belongs
to the class of those which take place with unusual facility, and are,
therefore, very often taken advantage of in practice, and also have
been and are going on in nature at every step. We will now consider the
reactions of oxides in the state of hydrates, not losing sight of the
fact that water is itself an oxide with definite properties, and has,
therefore, no little influence on the course of those changes in which
it takes part.
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