The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
If we take a definite quantity of an acid, and add an infusion of litmus
to it, it turns red; the addition of an alkaline solution does not
immediately alter the red colour of the litmus, but on adding more and
more of the alkaline solution a point is reached when the red colour
changes to violet, and then the further addition of a fresh quantity
of the alkaline solution changes the colour to blue. This change of
the colour of the litmus is a consequence of the formation of a new
compound. This reaction is termed the _saturation_ or _neutralisation_
of the acid by the base, or _vice versâ_. The solution in which the acid
properties of the acid are saturated by the alkaline properties of the
base is termed a _neutral_ solution. Such a solution, although derived
from the mixture of a base with an acid, does not exhibit either the
acid or basic reaction on litmus, yet it preserves many other signs of
the acid and alkali. It is observed that in such a definite admixture
of an acid with an alkali, besides the changes in the colour of litmus
there is a heating effect--_i.e._ an evolution of heat--which is alone
sufficient to prove that there was chemical action. And, indeed, if the
resultant violet solution be evaporated, there separates out, not the
acid or the alkali originally taken, but a substance which has neither
acid nor alkaline properties, but is usually solid and crystalline,
having a saline appearance; this is a _salt_ in the chemical sense of
the word. Hence a salt is derived from the reaction of an acid on an
alkali, in a certain definite proportion. The water here taken for
solution plays no other part than merely facilitating the progress
of the reaction. This is seen from the fact that the anhydrides of
the acids are able to combine with basic oxides, and give the same
salts as do the acids with the alkalis or hydrates. Hence, a salt is a
compound of definite quantities of an acid with an alkali. In the latter
reaction, water is separated out if the substance formed be the same
as is produced by the combination of anhydrous oxides together.[51]
Examples of the formation of salts from acids and bases are easily
observed, and are very often applied in practice. If we take, for
instance, insoluble magnesium oxide (magnesia) it is easily dissolved
in sulphuric acid, and on evaporation gives a saline substance, bitter,
like all the salts of magnesium, and familiar to all under the name of
Epsom salts, used as a purgative. If a solution of caustic soda--which
is obtained, as we saw, by the action of water on sodium oxide--be
poured into a flask in which charcoal has been burnt; or if carbonic
anhydride, which is produced under so many circumstances, be passed
through a solution of caustic soda, then sodium carbonate or soda,
Na_{2}CO_{3}, is obtained, of which we have spoken several times, and
which is prepared on a large scale and often used in manufactures. This
reaction is expressed by the equation, 2NaHO + CO_{2} = Na_{2}CO_{3} +
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