The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[54] Carbonic anhydride evolves heat in dissolving in water. The
solution easily dissociates and evolves carbonic anhydride,
according to the law of Henry and Dalton (_see_ Chapter I.)
In dissolving in caustic soda, it either gives a normal salt,
Na_{2}CO_{3}, which does not evolve carbonic anhydride, or an
acid salt, NaHCO_{3} which easily evolves carbonic anhydride when
heated. The same gas, when dissolved in solutions of salts, acts
in one or the other manner (_see_ Chapter II., Note 38). Here
it is seen what a successive series of relations exists between
compounds of a different order, between substances of different
degrees of stability. By making a distinction between the
phenomena of solutions and chemical compounds, we overlook those
natural transitions which in reality exist.
Judging from the above, a salt is a compound of basic and acid oxides,
or the result of the action of hydrates of these classes on each other
with separation of water. But salts may be obtained by other methods. It
must not be forgotten that basic oxides are formed by metals, and acid
oxides usually by non-metals. But metals and non-metals are capable of
combining together, and a salt is frequently formed by the oxidation of
such a compound. For example, iron very easily combines with sulphur,
forming iron sulphide FeS (as we saw in the Introduction); this in
air, and especially moist air, absorbs oxygen, with the formation of
the same salt FeSO_{4}, that may be obtained by the combination of the
oxides of iron and sulphur, or of the hydrates of these oxides. Hence,
it cannot be said or supposed that a salt has the properties of the
oxides, or must necessarily contain two kinds of oxides in itself.
The derivation of salts from oxides is merely one of the methods of
their preparation. We saw, for instance, that in sulphuric acid it was
possible to replace the hydrogen by zinc, and that by this means zinc
sulphate was formed; so likewise the hydrogen in many other acids may be
replaced by zinc, iron, potassium, sodium, and a whole series of similar
metals, corresponding salts being obtained. The hydrogen of the acid,
in all these cases, is exchanged for a metal, and a salt is obtained
from the hydrate. Regarding a salt from this point of view, it may be
said that _a salt is an acid in which hydrogen is replaced by a metal_.
This definition shows that a salt and an acid are essentially compounds
of the same series, with the difference that the latter contains
hydrogen and the former a metal. Such a definition is more exact than
the first definition of salts, inasmuch as it likewise includes those
acids which do not contain oxygen, and, as we shall afterwards learn,
there is a series of such acids. Such elements as chlorine and bromine
form compounds with hydrogen in which the hydrogen may be replaced by
a metal, forming substances which, in their reactions and external
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