The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
characters, resemble the salts formed from oxides. Table salt, NaCl, is
an example of this. It may be obtained by the replacement of hydrogen
in hydrochloric acid, HCl, by the metal sodium, just as sulphate of
sodium, Na_{2}SO_{4}, may be obtained by the replacement of hydrogen in
sulphuric acid, H_{2}SO_{4}, by sodium. The exterior appearance of the
resulting products, their neutral reaction, and even their saline taste,
show their resemblance to one another.
To the fundamental properties of salts yet another must be
added--namely, that they are more or less _decomposed by the action of a
galvanic current_. The results of this decomposition are very different
according to whether the salt be taken in a fused or dissolved state.
But the decomposition may generally be so represented, that the metal
appears at the electro-negative pole or cathode (like hydrogen in the
decomposition of water, or its mixture with sulphuric acid), and the
remaining parts of the salt appear at the electro-positive pole or anode
(where the oxygen of water appears). If, for instance, an electric
current acts on an aqueous solution of sodium sulphate, then the sodium
appears at the negative pole, and oxygen and the anhydride of sulphuric
acid at the positive pole. But in the solution itself the result is
different, for sodium, as we know, decomposes water with evolution of
hydrogen, forming caustic soda; consequently hydrogen will be evolved,
and caustic soda appear at the negative pole: while at the positive
pole the sulphuric anhydride immediately combines with water and forms
sulphuric acid, and therefore oxygen will be evolved and sulphuric acid
formed round this pole.[55] In other cases, when the metal separated is
not able to decompose water, it will be deposited in a free state. Thus,
for example, in the decomposition of copper sulphate, copper separates
out at the cathode, and oxygen and sulphuric acid appear at the anode,
and if a copper plate be attached to the positive pole, then the oxygen
evolved will oxidise the copper, and the oxide of copper will dissolve
and be deposited at the negative pole--that is, a transfer of copper
from the positive to the negative pole ensues. The galvanoplastic art
(electro-typing) is based on this principle.[56] Therefore the most
radical and general properties of salts (including also such salts as
table salt, which contain no oxygen) may be expressed by representing
the salt as composed of a metal M and a haloid X--that is, by expressing
the salt by MX. In common table salt the metal is sodium, and the haloid
an elementary body, chlorine. In sodium sulphate, Na_{2}SO_{4}, sodium
is again the metal, but the complex group, SO_{4}, is the haloid. In
sulphate of copper, CuSO_{4}, the metal is copper and the haloid the
same as in the preceding salt. Such a representation of salts expresses
with great simplicity the _capacity of every salt to enter into saline
double decompositions with other salts_; consisting in the mutual
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