The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[34] As chemical reactions are effected by heating, so the heat
absorbed by substances before decomposition or change of
state, and called 'specific heat,' goes in many cases to the
preparation, if it may be so expressed, of reaction, even when
the limit of the temperature of reaction is not attained. The
molecules of a substance A, which is not able to react on a
substance B below a temperature _t_, by being heated from a
somewhat lower temperature to _t_, undergoes that change which
had to be arrived at for the formation of A B.
For the comprehension of chemical phenomena as mechanical
processes--_i.e._, the study of the _modus operandi_ of chemical
phenomena--it is most important to consider: (1) the facts gathered
from stoïchiometry, or that part of chemistry which treats of the
quantitative relation, by weight or volume, of the reacting substances;
(2) the distinction between the different forms and classes of
chemical reactions; (3) the study of the changes in properties
produced by alteration in composition; (4) the study of the phenomena
which accompany chemical transformation; (5) a generalisation of the
conditions under which reactions occur. As regards stoïchiometry,
this branch of chemistry has been worked out most thoroughly, and
comprises laws (of Dalton, Avogadro-Gerhardt, and others) which bear
so deeply on all parts of chemistry that at the present time the chief
problem of chemical research consists in the application of general
stoïchiometrical laws to concrete examples, _i.e._, the quantitative
(volumetric or gravimetric) composition of substances. All other
branches of chemistry are clearly subordinate to this most important
portion of chemical knowledge. Even the very signification of reactions
of combination, decomposition, and rearrangement, acquired, as we shall
see, a particular and new character under the influence of the progress
of exact ideas concerning the quantitative relations of substances
entering into chemical changes. Furthermore, in this sense there arose
a new--and, till then, unknown--division of compound substances into
_definite_ and _indefinite_ compounds. Even at the beginning of this
century, Berthollet had not made this distinction. But Prout showed
that a number of compounds contain the substances of which they are they
break up, in exact definite proportions by weight, which are unalterable
under any conditions. Thus, for example, red mercury oxide always
contains sixteen parts by weight of oxygen for every 200 parts by weight
of mercury, which is expressed by the formula HgO. But in an alloy of
copper and silver one or the other metal may be added at will, and in an
aqueous solution of sugar, the relative proportion of the sugar and water
may be altered and nevertheless a homogeneous whole with the sum of the
independent properties will be obtained--_i.e._, in these cases there was
indefinite chemical combination.
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