The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Although in nature and chemical practice
the formation of indefinite compounds (such as alloys and solutions)
plays as essential a part as the formation of definite chemical
compounds, yet, as the stoïchiometrical laws at present apply chiefly to
the latter, all facts concerning indefinite compounds suffer from
inexactitude, and it is only during recent years that the attention of
chemists has been directed to this province of chemistry.
In chemical mechanics it is, from a qualitative point of view, very
important to clearly distinguish at the very beginning between
_reversible_ and _non-reversible reactions_. Substances capable of
reacting on each other at a certain temperature produce substances which
at the same temperature either can or cannot give back the original
substances. For example, salt dissolves in water at the ordinary
temperature, and the solution so obtained is capable of breaking up
at the same temperature, leaving salt and separating the water by
evaporation. Carbon bisulphide is formed from sulphur and carbon at
about the same temperature at which it can be resolved into sulphur
and carbon. Iron, at a certain temperature, separates hydrogen from
water, forming iron oxide, which, in contact with hydrogen at the same
temperature, is able to produce iron and water. It is evident that if
two substances, A and B, give two others C and D, and the reaction be
reversible, then C and D will form A and B, and, consequently, by taking
a definite mass of A and B, or a corresponding mass of C and D, we shall
obtain, in each case, all four substances--that is to say, there will be
a state of _chemical equilibrium_ between the reacting substances. By
increasing the mass of one of the substances we obtain a new condition
of equilibrium, so that reversible reactions present a means of studying
the _influence of mass_ on the _modus operandi_ of chemical changes.
Many of those reactions which occur with very complicated compounds or
mixtures may serve as examples of non-reversible reactions. Thus many of
the compound substances of animal and vegetable organisms are broken up
by heat, but cannot be re-formed from their products of decomposition at
any temperature. Gunpowder, as a mixture of sulphur, nitre, and carbon,
on being exploded, forms gases from which the original substances cannot
be re-formed at any temperature. In order to obtain them, recourse
must be had to an indirect method _of combination at the moment of
separation_. If A does not under any circumstances combine directly
with B, it does not follow that it cannot give a compound A B. For A
can often combine with C and B with D, and if C has a great affinity
for D, then the reaction of A C or B D produces not only C D, but also
A B. As on the formation of C D, the substances A and B (previously in
A C and B D) are left in a peculiar state of separation, it is supposed
that their mutual combination occurs because they meet together in this
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