The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
As regards those phenomena which accompany chemical action, the most
important circumstance in reference to chemical mechanics is that not
only do chemical processes produce a mechanical displacement (a motion
of particles), heat, light, electrical potential and current; but that
all these agents are themselves capable of changing and governing
chemical transformations. This reciprocity or reversibility naturally
depends on the fact that all the phenomena of nature are only different
kinds and forms of visible and invisible (molecular) motions. First
sound, and then light, was shown to consist of vibratory motions, as
the laws of physics have proved and developed beyond a doubt. The
connection between heat and mechanical motion and work has ceased to
be a supposition, but has become an accepted fact, and the mechanical
equivalent of heat (425 kilogrammetres of mechanical work correspond
with one kilogram unit of heat or Calorie) gives a mechanical measure
for thermal phenomena. Although the mechanical theory of electrical
phenomena cannot be considered so fully developed as the theory of heat,
both statical and dynamical electricity are produced by mechanical
means (in common electrical machines or in Gramme or other dynamos),
and conversely, a current (in electric motors) can produce mechanical
motion. Thus by connecting a current with the poles of a Gramme dynamo
it may be made to revolve, and, conversely, by rotating it an electrical
current is produced, which demonstrates the reversibility of electricity
into mechanical motion. Accordingly chemical mechanics must look for
the fundamental lines of its advancement in the correlation of chemical
with physical and mechanical phenomena. But this subject, owing to its
complexity and comparative novelty, has not yet been expressed by a
harmonious theory, or even by a satisfactory hypothesis, and therefore
we shall avoid lingering over it.
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