The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
_nascent state_ at the moment of separation (_in statu nascendi_). Thus
chlorine does not directly combine with charcoal, graphite, or diamond;
there are, nevertheless, compounds of chlorine with carbon, and many
of them are distinguished by their stability. They are obtained in the
action of chlorine on hydrocarbons, as the separation products from the
direct action of chlorine on hydrogen. Chlorine takes up the hydrogen,
and the carbon liberated at the moment of its separation, enters into
combination with another portion of the chlorine, so that in the end the
chlorine is combined with both the hydrogen and the carbon.[35]
[35] It is possible to imagine that the cause of a great many of such
reactions is, that substances taken in a separate state, for
instance, charcoal, present a complex molecule composed of
separate atoms of carbon which are fastened together (united, as
is usually said) by a considerable affinity; for atoms of the
same kind, just like atoms of different kinds, possess a mutual
affinity. The affinity of chlorine for carbon, although unable
to break this bond asunder, may be sufficient to form a stable
compound with atoms of carbon, which are already separate. Such
a view of the subject presents a hypothesis which, although
dominant at the present time, is without sufficiently firm
foundation. It is evident, however, that not only does chemical
reaction itself consist of motions, but that in the compound
formed (in the molecules) the elements (atoms) forming it are in
harmonious stable motion (like the planets in the solar system),
and this motion will affect the stability and capacity for
reaction, and therefore the mechanical side of chemical action
must be exceedingly complex. Just as there are solid, physically
constant non-volatile substances like rock, gold, charcoal,
&c., so are there stable and chemically constant bodies; while
corresponding to physically volatile substances there are bodies
like camphor, which are chemically unstable and variable.
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