The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
(_b_) _The influence of an electric current_, and of electricity in
general, on the progress of chemical transformations is very similar
to the influence of heat. The majority of compounds which conduct
electricity are decomposed by the action of a galvanic current, and as
there is great similarity in the conditions under which decomposition
and combination proceed, combination often proceeds under the influence
of electricity. Electricity, like heat, must be regarded as a peculiar
form of molecular motion, and all that refers to the influence of heat
also refers to the phenomena produced by the action of an electrical
current, with this difference, only that a substance can be separated
into its component parts with much greater ease by electricity, since
the process goes on at the ordinary temperature. The most stable
compounds may be decomposed by this means, and a most important fact
is then observed--namely, that the component parts appear at the
different poles of electrodes by which the current passes through the
substance. Those substances which appear at the positive pole (anode)
are called 'electro-negative,' and those which appear at the negative
pole (cathode, that in connection with the zinc of an ordinary galvanic
battery) are called 'electro-positive.' The majority of non-metallic
elements, such as chlorine, oxygen, &c., and also acids and substances
analogous to them, belong to the first group, whilst the metals,
hydrogen, and analogous products of decomposition appear at the negative
pole. Chemistry is indebted to the decomposition of compounds by the
electric current for many most important discoveries. Many elements
have been discovered by this method, the most important being potassium
and sodium. Lavoisier and the chemists of his time were not able to
decompose the oxygen compounds of these metals, but Davy showed that
they might be decomposed by an electric current, the metals sodium and
potassium appearing at the negative pole. Now that the dynamo gives the
possibility of producing an electric current by the combustion of fuel,
this method of Sir H. Davy is advantageously employed for obtaining
metals, &c. on a large scale, for instance, sodium from fused caustic
soda or chlorine from solutions of salt.
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