The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
(_c_) Certain unstable compounds are also decomposed by _the action of
light_. Photography is based on this property in certain substances
(for instance, in the salts of silver). The mechanical energy of those
vibrations which determine the phenomena of light is very small, and
therefore only certain, and these generally unstable, compounds can be
decomposed by light--at least under ordinary circumstances. But there is
one class of chemical phenomena dependent on the action of light which
forms as yet an unsolved problem in chemistry--these are the processes
accomplished in plants under the influence of light. Here there take
place most unexpected decompositions and combinations, which are often
unattainable by artificial means. For instance, carbonic anhydride,
which is so stable under the influence of heat and electricity, is
decomposed and evolves oxygen in plants under the influence of light. In
other cases, light decomposes unstable compounds, such as are usually
easily decomposed by heat and other agents. Chlorine combines with
hydrogen under the influence of light, which shows that combination, as
well as decomposition, can be determined by its action, as was likewise
the case with heat and electricity.
(_d_) _Mechanical causes_ exert, like the foregoing agents, an action
both on the process of chemical combination and of decomposition. Many
substances are decomposed by friction or by a blow--as, for example,
the compound called iodide of nitrogen (which is composed of iodine,
nitrogen, and hydrogen), and silver fulminate. Mechanical friction
causes sulphur to burn at the expense of the oxygen contained in
potassium chlorate. Pressure affects both the physical and chemical
state of the reacting substances, and, together with the temperature,
determines the state of a substance. This is particularly evident when
the substance occurs in an elastic-gaseous form since the volume, and
hence also the number of points of encounter between the reacting
substances is greatly altered by a change of pressure. Thus, under equal
conditions of temperature, hydrogen when compressed acts more powerfully
upon iodine and on the solutions of many salts.
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