The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
(_e_) Besides the various conditions which have been enumerated above,
the progress of chemical reactions is accelerated or retarded by the
_condition of contact_ in which the reacting bodies occur. Other
conditions remaining constant, the rate of progress of a chemical
reaction is accelerated by increasing the number of points of contact.
It will be enough to point out the fact that sulphuric acid does not
absorb ethylene under ordinary conditions of contact, but only after
continued shaking, by which means the number of points of contact
is greatly increased. To ensure complete action between solids, it
is necessary to reduce them to very fine powder and to mix them as
thoroughly as possible. M. Spring, the Belgian chemist, has shown
that finely powdered solids which do not react on each other at the
ordinary temperature may do so under an increased pressure. Thus, under
a pressure of 6,000 atmospheres, sulphur combines with many metals at
the ordinary temperature, and mixtures of the powders of many metals
form alloys. It is evident that an increase in the number of points
or surfaces must be regarded as the chief cause producing reaction,
which is doubtless accomplished in solids, as in liquids and gases, in
virtue of an internal motion of the particles, which motion, although
in different degrees and forms, must exist in all the states of matter.
It is very important to direct attention to the fact that the internal
motion or condition of the parts of the particles of matter must be
different on the surface of a substance from what it is inside; because
in the interior of a substance similar particles are acting on all sides
of every particle, whilst at the surface they act on one side only.
Therefore, the condition of a substance at its surfaces of contact with
other substances must be more or less modified by them--it may be in a
manner similar to that caused by an elevation of temperature. These
considerations throw some light on the action in the large class of
_contact reactions_; that is, such as appear to proceed from the mere
presence (contact) of certain special substances. Porous or powdery
substances are very prone to act in this way, especially spongy platinum
and charcoal. For example, sulphurous anhydride does not combine
directly with oxygen, but this reaction takes place in the presence of
spongy platinum.[36]
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account