The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
_f_, where _f_ is the pressure of the vapour according to the
tables of vapour tension. Thus, if a volume N of a gas saturated
with moisture be measured at a pressure H, then the volume of
the gas, when dry, will be equal to N[(H-f)/H]. In fact, the
entire volume N must be to the volume of dry gas _x_ as H is to
H-_f_; therefore, N : _x_ = H : H-_f_, from which _x_ = N[(H-f)/H].
Under any other pressure--for instance, 760 mm.--The volume of
dry gas will be _x_H/760, or (H-_f_)/760, and we thus obtain
the following practical rule: If a volume of a gas saturated
with aqueous vapour be measured at a pressure H mm., then the
volume of dry gas contained in it will be obtained by finding the
volume corresponding to the pressure H, less the pressure due
to the aqueous vapour at the temperature observed. For example,
37·5 cubic centimetres of air saturated with aqueous vapour were
measured at a temperature of 15·3°, and under a pressure of 747·3
mm. of mercury (at 0°). What will be the volume of dry gas at 0°
and 760 mm.?
The pressure of aqueous vapour corresponding to 15·3° is equal to
12·9 mm., and therefore the volume of dry gas at 15·3° and 747·3
mm. is equal to 37·5 × (747·3-12·9)/747·3; at 760 mm. it will be
equal to 37·5 × (734·4/760); and at 0° the volume of dry gas will
be 37·5 × (734·4/760) × 273/(273 + 15·3) = 34·31 c.c.
From this rule may also be calculated what fraction of a volume
of gas is occupied by moisture under the ordinary pressure at
different temperatures; for instance, at 30° C. _f_ = 31·5,
consequently 100 volumes of a moist gas or air, at 760 mm.,
contain a volume of aqueous vapour 100 × (31·5/760), or 4·110; it
is also found that at 0° there is contained 0·61 p.c. by volume,
at 10° 1·21 p.c., at 20° 2·29 p.c., and at 50° up to 12·11 p.c.
From this it may be judged how great an error might be made in
the measurement of gases by volume if the moisture were not taken
into consideration. From this it is also evident how great are
the variations in volume of the atmosphere when it loses or gains
aqueous vapour, which again explains a number of atmospheric
phenomena (winds, variation of pressure, rainfalls, storms, &c.)
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