The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
If a gas is not saturated, then it is indispensable that the
degree of moisture should be known in order to determine the
volume of dry gas from the volume of moist gas. The preceding
ratio gives the maximum quantity of water which can be held in
a gas, and the degree of moisture shows what fraction of this
maximum quantity occurs in a given case, when the vapour does
not saturate the space occupied by the gas. Consequently, if the
degree of moisture equals 50 p.c.--that is, half the maximum--then
the volume of dry gas at 760 mm. is equal to the volume of dry
gas at 760 mm. multiplied by (_h_-0·5_f_)/760, or, in general, by
(_h_-_rf_)/760 where _r_ is the degree of moisture. Thus, if it
is required to measure the volume of a moist gas, it must either
be thoroughly dried or quite saturated with moisture, or else
the degree of moisture determined. The first and last methods
are inconvenient, and therefore recourse is usually had to the
second. For this purpose water is introduced into the cylinder
holding the gas to be measured; it is left for a certain time so
that the gas may become saturated, the precaution being taken
that a portion of the water remains in a liquid state; then the
volume of the moist gas is determined, from which that of the
dry gas may be calculated. In order to find the _weight of the
aqueous vapour_ in a gas it is necessary to know the weight of a
cubic measure at 0° and 760 mm. Knowing that one cubic centimetre
of air in these circumstances weighs 0·001293 gram, and that
the density of aqueous vapour is 0·62, we find that one cubic
centimetre of aqueous vapour at 0° and 760 mm. weighs 0·0008 gram,
and at a temperature _t_° and pressure _h_ the weight of one cubic
centimetre will be 0·0008 × _h_/760 × 273/(273 + _t_). We already
know that _v_ volumes of a gas at a temperature _t_° pressure _h_
contain _v_ × _f_/_h_ volumes of aqueous vapour which saturate it,
therefore the weight of the aqueous vapour held in _v_ volumes of
a gas will be
_v_ x 0·0008 × _f_/760 × 273/(273 + _t_).
Accordingly, the weight of water which is contained in one volume
of a gas depends only on the temperature and not on the pressure.
This also signifies that evaporation proceeds to the same extent
in air as in a vacuum, or, in general terms (this is _Dalton's
law_), vapours and gases diffuse into each other as if into a
vacuum. In a given space, at a given temperature, a constant
quantity of vapour enters, whatever be the pressure of the gas
filling that space.
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