The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
From this it is clear that if the weight of the vapour contained
in a given volume of a gas be known, it is easy to determine the
degree of moisture _r_ = _p_/(_v_ × 0·0008) × 760/_t_ × (273 +
_t_)/273. On the is founded the very exact determination of the
degree of moisture of air by the weight of water contained in a
given volume. It is easy to calculate from the preceding formula
the number of grams of water contained at any pressure in one
cubic metre or million cubic centimetres of air saturated with
vapour at various temperatures; for instance, at 30° _f_ = 31·5,
hence _p_ = 29·84 grams.
The laws of Mariotte, Dalton, and Gay-Lussac, which are here
applied to gases and vapours, are not entirely exact, but are
approximately true. If they were quite exact, a mixture of several
liquids, having a certain vapour pressure, would give vapours of
a very high pressure, which is not the case. In fact the pressure
of aqueous vapour is slightly less in a gas than in a vacuum,
and the weight of aqueous vapour held in a gas is slightly less
than it should be according to Dalton's law, as was shown by the
experiments of Regnault and others. This means that the tension
of the vapour is less in air than in a vacuum. The difference
does not, however, exceed 5 per cent. of the total pressure of
the vapours. This _decrement in vapour tension_ which occurs in
the intermixture of vapours and gases, although small, indicates
that there is then already, so to speak, a beginning of chemical
change. The essence of the matter is that in this case there
occurs, as on contact (see preceding footnote), an alteration in
the motions of the atoms in the molecules, and therefore also a
change in the motion of the molecules themselves.
In the uniform intermixture of air and other gases with aqueous
vapour, and in the capacity of water to pass into vapour and
form a uniform mixture with air, we may perceive an instance of
a physical phenomenon which is analogous to chemical phenomena,
forming indeed a transition from one class of phenomena to
the other. Between water and dry air there exists a kind of
affinity which obliges the water to saturate the air. But such a
homogeneous mixture is formed (almost) independently of the nature
of the gas in which evaporation takes place; even in a vacuum
the phenomenon occurs in exactly the same way as in a gas, and
therefore it is not the property of the gas, nor its relation to
water, but the property of the water itself, which compels it to
evaporate, and therefore in this case chemical affinity is not yet
operative--at least its action is not clearly pronounced. That it
does, however, play a certain part is seen from the deviation from
Dalton's law.
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