The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Distilled water may be prepared, or distillation in general
carried on, either in a metal still with worm condenser (fig. 4)
or on a small scale in the laboratory in a glass retort (fig.
5) heated by a lamp. Fig. 5 illustrates the main parts of the
usual glass laboratory apparatus used for distillation. The steam
issuing from the retort (on the right-hand side) passes through a
glass tube surrounded by a larger tube, through which a stream of
cold water passes, by which the steam is condensed, and runs into
a receiver (on the left-hand side).
[Illustration: FIG. 5.--Distillation from a glass retort. The neck
of the retort fits into the inner tube of the Liebig's condenser.
The space between the inner and outer tube of the condenser is
filled with cold water, which enters by the tube _g_ and flows out
at _f_.]
[8] One of Lavoisier's first memoirs (1770) referred to this question.
He investigated the formation of the earthy residue in the
distillation of water in order to prove whether it was possible,
as was affirmed, to convert water into earth, and he found that
the residue was produced by the action of water on the sides of
the vessel containing it, and not from the water itself. He proved
this to be the case by direct weighing.
For certain physical and chemical researches, however, it is necessary
to have perfectly pure water. To obtain it, a solution of potassium
permanganate is added to distilled water until the whole is a light
rose colour. By this means the organic matter in the water is destroyed
(converted into gases or non-volatile substances). An excess of
potassium permanganate does no harm, because in the next distillation it
is left behind in the distillation apparatus. The second distillation
should take place in a platinum retort with a platinum receiver.
Platinum is a metal which is not acted on either by air or water, and
therefore nothing passes from it into the water. The water obtained
in the receiver still contains air. It must then be boiled for a long
time, and afterwards cooled in a vacuum under the receiver of an air
pump. Pure water does not leave any residue on evaporation; does not
in the least change, however long it be kept; does not decompose like
water only once distilled or impure; and it does not give bubbles of
gas on heating, nor does it change the colour of a solution of potassium
permanganate.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account