The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Water, purified as above described, has constant _physical_ and
_chemical properties_. For instance, it is of such water only that
one cubic centimetre weighs one gram at 4° C.--_i.e._ it is only such
pure water whose specific gravity equals 1 at 4° C.[9] Water in a
solid state forms crystals of the hexagonal system[10] which are seen
in snow, which generally consists of star-like clusters of several
crystals, and also in the half-melted scattered ice floating on rivers
in spring time. At this time of the year the ice splits up into spars
or prisms, bounded by angles proper to substances crystallising in the
hexagonal system.
[9] Taking the generally-accepted specific gravity of water at its
greatest density--_i.e._ at 4° as one--it has been shown by
experiment that the specific gravity of water at different
temperatures is as follows:
At 0° 0·99987 | At 30° 0·99574
" +10° 0·99974 | " 40° 0·99233
" 15° 0·99915 | " 50° 0·98817
" 20° 0·99827 | " 100° 0·95859
A comparison of all the data at present known shows that the
variation of the specific gravity S_{t} with the temperature
_t_ (determined by the mercurial thermometer) maybe expressed
(Mendeléeff 1891) by the formula
S_{t} = 1 - (_t_-4)^{2}/(94·1 + _t_) (703·51-_t_) 1·9
+-----------+-------------+---------------------------+-----------+
| t° C. | | Variation of sp. gr. with | |
| according |Sp. gr. S_{t}| a rise of | Volume |
| to the |(at 4° = +--------------+------------+taking vol.|
| mercurial | 1,000,000) |Temp. per 1°C.|Pressure per| at 4° = 1 |
|thermometer| | or ds/dt |1 atmosphere| |
| | | | or ds/dp | |
+-----------+-------------+--------------+------------+-----------+
| -10 | 998,281 | +264 | +54 | 1,001,722 |
| 0 | 999,873 | +65 | +50 | 1,000,127 |
| 10 | 999,738 | -85 | +47 | 1,000,262 |
| 20 | 998,272 | -203 | +45 | 1,001,731 |
| 30 | 995,743 | -299 | +43 | 1,004,276 |
| 50 | 988,174 | -450 | +40 | 1,011,967 |
| 70 | 977,948 | -569 | +39 | 1,022,549 |
| 90 | 965,537 | -670 | +41 | 1,035,692 |
| 100 | 958,595 | -718 | +42 | 1,043,194 |
| 120 | 943,814 | -810 | +43 | 1,060,093 |
| 160 | 907,263 | -995 | +55 | 1,102,216 |
| 200 | 863,473 | -1,200 | +73 | 1,158,114 |
+-----------+-------------+--------------+------------+-----------+
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