The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
If the temperature be determined by the hydrogen thermometer,
whose indications between 0° and 100° are slightly lower than the
mercurial (for example, about 0·1° C. at 20°), then a slightly
smaller sp. gr. will be obtained for a given _t_. Thus Chappuis
(1892) obtained 0·998233 for 20°. Water at 4° is taken as the
basis for reducing measures of length to measures of weight and
volume. The _metric, decimal, system_ of measures of weights and
volumes is generally employed in science. The starting point of
this system is the metre (39·37 inches) divided into decimetres
(= 0·1 metre), centimetres (= 0·01 metre), millimetres (= 0·001
metre), and micrometres (= one millionth of a metre). A cubic
decimetre is called a _litre_, and is used for the measurement
of volumes. The weight of a litre of water at 4° in a vacuum is
called a kilogram. One thousandth part of a kilogram of water
weighs one _gram_. It is divided into decigrams, centigrams,
and milligrams (= 0·001 gram). An English pound equals 453·59
grams. The great advantage of this system is that it is a decimal
one, and that it is universally adopted in science and in most
international relations. _All the measures cited in this work are
metrical._ The units most often used in science are:--Of length,
the centimetre; of weight, the gram; of time, the second; of
temperature, the degree Celsius or Centigrade. According to the
most trustworthy determinations (Kupfer in Russia 1841, and Chaney
in England 1892), the weight of a c. dcm. of water at 4° in vacuo
is about 999·9 grms. For ordinary purposes the weight of a c.
dcg. may be taken as equal to a kg. Hence the litre (determined
by the weight of water it holds) is slightly greater than a cubic
decimetre.
[10] As solid substances appear in independent, regular, crystalline
forms which are dependent, judging from their cleavage or
lamination (in virtue of which mica breaks, up into laminae,
and Iceland spar, &c., into pieces bounded by faces inclined to
each other at angles which are definite for each substance), on
an inequality of attraction (cohesion, hardness) in different
directions which intersect at definite angles the determination
of crystalline form therefore affords one of the most important
characteristics for identifying definite chemical compounds. The
elements of crystallography which comprise a special science
should therefore he familiar to all who desire to work in
scientific chemistry. In this work we shall only have occasion
to speak of a few crystalline forms, some of which are shown in
figs. 6 to 12.
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