The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[11] Of all known liquids, water exhibits the greatest _cohesion_ of
particles. Indeed, it ascends to a greater height in capillary
tubes than other liquids; for instance, two and a half times as
high as alcohol, nearly three times as high as ether, and to a
much greater height than oil of vitriol, &c. In a tube one mm. in
diameter, water at 0° ascends 15·3 mm., measuring from the height
of the liquid to two-thirds of the height of the meniscus, and at
100° it rises 12·5 mm. The cohesion varies very uniformly with
the temperature; thus at 50° the height of the capillary column
equals 13·9 mm.--that is, the mean between the columns at 0°
and 100°. This uniformity is not destroyed even at temperatures
near the freezing point, and hence it may be assumed that at
high temperatures cohesion will vary as uniformly as at ordinary
temperatures; that is, the difference between the columns at 0°
and 100° being 2·8 mm., the height of the column at 500° should
be 15·2-(5 × 2·8) = 1·2 mm.; or, in other words, at these high
temperatures the cohesion between the particles of water would he
almost _nil_. Only certain solutions (sal ammoniac and lithium
chloride), and these only with a great excess of water, rise
higher than pure water in capillary tubes. The great cohesion of
water doubtless determines many of both its physical and chemical
properties.
The quantity of heat required to raise the temperature of one
part by weight of water from 0° to 1°, _i.e._ by 1° C., is called
the _unit of heat_ or calorie; the _specific heat of liquid
water_ at 0° is taken as equal to unity. The variation of this
specific heat with a rise in temperature is inconsiderable in
comparison with the variation exhibited by the specific heats of
other liquids. According to Ettinger, the specific heat of water
at 20° = 1·016, at 50° = 1·039, and at 100° = 1·073. The specific
heat of water is greater than that of any other known liquid;
for example, the specific heat of alcohol at 0° is 0·55--_i.e._
the quantity of heat which raises 55 parts of water 1° raises
100 parts of alcohol 1°. The specific heat of oil of turpentine
at 0° is 0·41, of ether 0·53, of acetic acid 0·5274, of mercury
0·033. Hence water is the best condenser or absorber of heat.
This property of water has an important significance in practice
and in nature. Water prevents rapid cooling or heating, and thus
tempers cold and heat. The specific heats of ice and aqueous
vapour are much less than that of water; namely, that of ice is
0·504, and of steam 0·48.
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