The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
With an increase in pressure equal to one atmosphere, the
compressibility of water (_see_ Note 9) is 0·000047, of mercury
0·00000352, of ether 0·00012 at 0°, of alcohol at 13° 0·000095.
The addition of various substances to water generally decreases
both its compressibility and cohesion. The compressibility of
other liquids increases with a rise of temperature, but for water
it decreases up to 53° and then increases like other liquids.
The _expansion of water_ by heat (Note 9) also exhibits many
peculiarities which are not found in other liquids. The expansion
of water at low temperatures is very small compared with other
liquids; at 4° it is almost zero, and at 100° it is equal to
0·0008; below 4° it is negative--_i.e._ water on cooling then
expands, and does not decrease in volume. In passing into a solid
state, the specific gravity of water decreases; at 0° one c.c.
of water weighs 0·999887 gram, and one c.c. of ice at the same
temperature weighs only 0·9175 gram. The ice formed, however,
contracts on cooling like the majority of other substances. Thus
100 volumes of ice are produced from 92 volumes of water--that
is, water expands considerably on freezing, which fact determines
a number of natural phenomena. The freezing point of water falls
with an increase in pressure (0·007° per atmosphere), because in
freezing water expands (Thomson), whilst with substances which
contract in solidifying the melting point rises with an increase
in pressure; thus, paraffin under one atmosphere melts at 46°,
and under 100 atmospheres at 49°.
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