The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
When liquid water passes into vapour, the cohesion of its
particles must be destroyed, as the particles are removed to
such a distance from each other that their mutual attraction
no longer exhibits any influence. As the cohesion of aqueous
particles varies at different temperatures, the quantity of heat
which is expended in overcoming this cohesion--or the _latent
heat of evaporation_--will for this reason alone be different at
different temperatures. The quantity of heat which is consumed in
the transformation of one part by weight of water, at different
temperatures, into vapour was determined by Regnault with great
accuracy. His researches showed that one part by weight of water
at 0°, in passing into vapour having a temperature _t_°, consumes
606·5 + 0·305_t_ units of heat, at 50° 621·7, at 100° 637·0, at
150° 652·2, and at 200° 667·5. But this quantity includes also
the quantity of heat required for heating the water from 0° to
_t_°--_i.e._ besides the latent heat of evaporation, also that
heat which is used in heating the water in a liquid state to a
temperature _t_°. On deducting this amount of heat, we obtain the
latent heat of evaporation of water as 606·5 at 0°, 571 at 50°,
534 at 100°, 494 at 150°, and only 453 at 200°, which shows that
the conversion of water at different temperatures into vapour
at a constant temperature requires very different quantities of
heat. This is chiefly dependent on the difference of the cohesion
of water at different temperatures; the cohesion is greater at
low than at high temperatures, and therefore at low temperatures
a greater quantity of heat is required to overcome the cohesion.
On comparing these quantities of heat, it will be observed that
they decrease rather uniformly, namely their difference between
0° and 100° is 72, and between 100° and 200° is 81 units of
heat. From this we may conclude that this variation will be
approximately the same for high temperatures also, and therefore
that no heat would be required for the conversion of water into
vapour at a temperature of about 400°. At this temperature, water
passes into vapour whatever be the pressure (see Chap. II. The
absolute boiling point of water, according to Dewar, is 370°,
the critical pressure 196 atmospheres). It must here be remarked
that water, in presenting a greater cohesion, requires a larger
quantity of heat for its conversion into vapour than other
liquids. Thus alcohol consumes 208, ether 90, turpentine 70,
units of heat in their conversion into vapour.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account