The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
The table shows the boiling points of water at different
pressures. Thus on the summit of Mont Blanc, where the average
pressure is about 424 mm., water boils at 84·4°. In a rarefied
atmosphere water boils even at the ordinary temperature, but in
evaporating it absorbs heat from the neighbouring parts, and
therefore it becomes cold and may even freeze if the pressure
does not exceed 4·6 mm., and especially if the vapour be rapidly
absorbed as it is formed. Oil of vitriol, which absorbs the
aqueous vapour, is used for this purpose. Thus ice may be
obtained artificially at the ordinary temperature with the aid
of an air-pump. This table of the tension of aqueous vapour also
shows the temperature of water contained in a closed boiler if
the pressure of the steam formed be known. Thus at a pressure
of five atmospheres (a pressure of five times the ordinary
atmospheric pressure--_i.e._ 5 × 760 = 3,800 mm.) the temperature
of the water would be 152°. The table also shows the pressure
produced on a given surface by steam on issuing from a boiler.
Thus steam having a temperature of 152° exerts a pressure of
517 kilos on a piston whose surface equals 100 sq. cm., for the
pressure of one atmosphere on one sq. cm. equals 1,033 kilos,
and steam at 152° has a pressure of five atmospheres. As a
column of mercury 1 mm. high exerts a pressure of 1·35959 grams
on a surface of 1 sq. cm., therefore the pressure of aqueous
vapour at 0° corresponds with a pressure of 6·25 grams per
square centimetre. The pressures for all temperatures may be
calculated in a similar way, and it will be found that at 100°
it is equal to 1,033·28 grams. This means that if a cylinder
be taken whose sectional area equals 1 sq. cm., and if water
be poured into it and it be closed by a piston weighing 1,033
grams, then on heating it in a vacuum to 100° no steam will be
formed, because the steam cannot overcome the pressure of the
piston; and if at 100° 534 units of heat be transmitted to each
unit of weight of water, then the whole of the water will be
converted into vapour having the same temperature; and so also
for every other temperature. The question now arises, to what
height does the piston rise under these circumstances? that is,
in other words, What is the volume occupied by the steam under
a known pressure? For this we must know the weight of a cubic
centimetre of steam at various temperatures. It has been shown by
experiment that the density of steam, which does not saturate a
space, varies very inconsiderably at all possible pressures, and
is nine times the density of hydrogen under similar conditions.
Steam which saturates a space varies in density at different
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account