The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
temperatures, but this difference is very small, and its
average density with reference to air is 0·64. We will employ
this number in our calculation, and will calculate what volume
the steam occupies at 100°. One cubic centimetre of air at 0°
and 760 mm. weighs 0·001293 gram, at 100° and under the same
pressure it will weigh 0·001293/1·368 or about 0·000946 gram,
and consequently one cubic centimetre of steam whose density
is 0·64 will weigh 0·000605 gram at 100°, and therefore one
gram of aqueous vapour will occupy a volume of about 1·653 c.c.
Consequently, the piston in the cylinder of 1 sq. cm. sectional
area, and in which the water occupied a height of 1 cm., will
be raised 1,653 cm. on the conversion of this water into steam.
This piston, as has been mentioned, weighs 1,033 grams, therefore
the _external work of the steam_--that is, that work which the
water does in its conversion into steam at 100°--is equal to
lifting a piston weighing 1,033 grams to a height of 1,653 cm.,
or 17·07 kilogram-metres of work--_i.e._ is capable of lifting
17 kilograms 1 metre, or 1 kilogram 17 metres. One gram of water
requires for its conversion into steam 534 gram units of heat or
0·534 kilogram unit of heat--_i.e._ the quantity of heat absorbed
in the evaporation of one gram of water is equal to the quantity
of heat which is capable of heating 1 kilogram of water 0·534°.
Each unit of heat, as has been shown by accurate experiment,
is capable of doing 424 kilogram-metres of work. Hence, in
evaporating, one gram of water expends 424 × 0·534 = (almost) 227
kilogram-metres of work. The external work was found to be only
17 kilogram-metres, therefore 210 kilogram-metres are expended in
overcoming the internal cohesion of the aqueous particles, and
consequently about 92 p.c. of the total heat or work is consumed
in overcoming the internal cohesion. The following figures are
thus calculated approximately:--
+------------+----------------+-----------------+--------------+
| | Total work of |External work of | |
|Temperature | evaporation in | vapour in | Internal |
| |kilogram-metres |kilogram-metres |work of vapour|
+------------+----------------+-----------------+--------------+
| 0° | 255 | 13 | 242 |
| 50° | 242 | 15 | 227 |
| 100° | 226 | 17 | 209 |
| 150° | 209 | 19 | 190 |
| 200° | 192 | 20 | 172 |
+------------+----------------+-----------------+--------------+
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account