The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Water is mechanically attracted by many substances; it adheres to their
surfaces just as dust adheres to objects, or one piece of polished glass
adheres to another. Such attraction is termed 'moistening,' 'soaking,'
or 'absorption of water.' Thus water moistens clean glass and adheres
to its surface, is absorbed by the soil, sand, and clay, and does
not flow away from them, but lodges itself between their particles.
Similarly, water soaks into a sponge, cloth, hair, or paper, &c., but
fat and greasy substances in general are not moistened. Attraction
of this kind does not alter the physical or chemical properties of
water. For instance, under these circumstances water, as is known from
everyday experience, may be expelled from objects by drying. Water
which is in any way held mechanically may be dislodged by mechanical
means, by friction, pressure, centrifugal force, &c. Thus water is
squeezed from wet cloth by pressure or centrifugal machines. But objects
which in practice are called dry (because they do not feel wet) often
still contain moisture, as may be proved by heating the object in a
glass tube closed at one end. By placing a piece of paper, dry earth,
or any similar object (especially porous substances) in such a glass
tube, and heating that part of the tube where the object is situated,
it will be remarked that water condenses on the cooler portions of
the tube. The presence of such absorbed, or 'hygroscopic,' water is
generally best detected in non-volatile substances by drying them at
100°, or under the receiver of an air-pump and over substances which
attract water chemically. By weighing a substance before and after
drying, it is easy to determine the amount of hygroscopic water from
the loss in weight.[13] Only in this case the amount of water must be
judged with care, because the loss in weight may sometimes proceed
from the decomposition of the substance itself, with disengagement of
gases or vapour. In making exact weighings the hygroscopic capacity
of substances--that is, their capacity to absorb moisture--must be
continually kept in view, as otherwise the weight will be untrue from
the presence of moisture. The quantity of moisture absorbed depends on
the degree of moisture of the atmosphere (that is, on the tension of the
aqueous vapour in it) in which a substance is situated. In an entirely
dry atmosphere, or in a vacuum, the hygroscopic water is expelled, being
converted into vapour; therefore, substances containing hygroscopic
water may be completely dried by placing them in a dry atmosphere or
in a vacuum. The process is aided by heat, as it increases the tension
of the aqueous vapour. Phosphoric anhydride (a white powder), liquid
sulphuric acid, solid and porous calcium chloride, or the white powder
of ignited copper sulphate, are most generally employed in drying
gases. They absorb the moisture contained in air and all gases to a
considerable, but not unlimited, extent. Phosphoric anhydride and
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account