The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
The work necessary for overcoming the internal cohesion of
water in its passage into vapour decreases with the rise in
temperature--that is, corresponds with the decrease of cohesion;
and, in fact, the variations which take place in this case are
very similar to those which are observed in the heights to which
water rises in capillary tubes at different temperatures. It is
evident, therefore, that the amount of external--or, as it is
termed, useful--work which water can supply by its evaporation
is very small compared with the amount which it expends in its
conversion into vapour.
In considering certain physico-mechanical properties of water, I
had in view not only their importance for theory and practice,
but also their purely chemical significance; for it is evident
from the above considerations that even in a physical change
of state the greatest part of the work done is employed in
overcoming cohesion, and that an enormous amount of internal
energy must be expended in overcoming chemical cohesion or
affinity.
[12] When it is necessary to heat a considerable mass of liquid in
different vessels, it would be very uneconomical to make use of
metallic vessels and to construct a separate furnace for each;
such cases are continually met with in practice. Steam from a
boiler is introduced into the liquid, or, in general, into the
vessel which it is required to heat. The steam, in condensing and
passing into a liquid state, parts with its latent heat, and as
this is very considerable a small quantity of steam will produce
a considerable heating effect. If it be required, for instance,
to heat 1,000 kilos of water from 20° to 50°, which requires
approximately 30,000 units of heat, steam at 100° is passed into
the water from a boiler. Each kilogram of water at 50° contains
about 50 units of heat, and each kilogram of steam at 100°
contains 637 units of heat; therefore, each kilogram of steam in
cooling to 50° gives up 587 units of heat, and consequently 52
kilos of steam are capable of heating 1,000 kilos of water from
20° to 50°. Water is very often applied for heating in chemical
practice. For this purpose metallic vessels or pans, called
'water-baths,' are made use of. They are closed by a cover formed
of concentric rings lying on each other. The vessels--such as
beakers, evaporating basins, retorts, &c.--containing liquids,
are placed on these rings, and the water in the bath is heated.
The steam given off heats the bottom of the vessels to be heated,
and thus effects the evaporation or distillation.
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