The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
In order to dry any substance at about 100°--that is, at the
boiling point of water (hygroscopic water passes off at this
temperature)--an apparatus called a 'drying-oven' is employed.
It consists of a double copper box; water is poured into the
space between the internal and external boxes, and the oven is
then heated over a stove or by any other means, or else steam
from a boiler is passed between the walls of the two boxes.
When the water boils, the temperature inside the inner box will
be approximately 100° C. The substance to be dried is placed
inside the oven, and the door is closed. Several holes are cut
in the door to allow the free passage of air, which carries
off the aqueous vapour by the chimney on the top of the oven.
Often, however, desiccation is carried on in copper ovens
heated directly over a lamp (fig. 13). In this case any desired
temperature may be obtained, which is determined by a thermometer
fixed in a special orifice. There are substances which only
part with their water at a much higher temperature than 100°,
and then such air baths are very useful. In order to determine
directly the amount of water in a substance which does not part
with anything except water at a red heat, the substance is placed
in a bulb tube. By first weighing the tube empty and then with
the substance to be dried in it, the weight of the substance
taken may be found. The tube is then connected on one side with
a gas-holder full of air, which, on opening a stop-cock, passes
first through a flask containing sulphuric acid, and then into a
vessel containing lumps of pumice stone moistened with sulphuric
acid. In passing through these vessels the air is thoroughly
dried, having given up all its moisture to the sulphuric acid.
Thus dry air will pass into the bulb tube, and as hygroscopic
water is entirely given up from a substance in dry air even at
the ordinary temperature, and still more rapidly on heating,
the moisture given up by the substance in the tube will be
carried off by the air passing through it. This damp air then
passes through a U-shaped tube full of pieces of pumice stone
moistened with sulphuric acid, which absorbs all the moisture
given off from the substance in the bulb tube. Thus all the water
expelled from the substance will collect in the [U] tube, and so,
if this be weighed before and after, the difference will show the
quantity of water expelled from the substance. If only water (and
not any gases) come over, the increase of the weight of the [U]
tube will be equal to the decrease in the weight of the bulb tube.
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