The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[14] Instead of under a glass bell jar, drying over sulphuric acid is
often carried on in a desiccator consisting of a shallow
wide-mouthed glass vessel, closed by a well-fitting ground-glass
cover. Sulphuric acid is poured over the bottom of the
desiccator, and the substance to be dried is placed on a glass
stand above the acid. A lateral glass tube with a stop-cock is
often fused into the desiccator in order to connect it with an
air pump, and so allow drying under a diminished pressure, when
the moisture evaporates more rapidly. The fact that in the usual
form of desiccator the desiccating substance (sulphuric acid) is
placed beneath the substance to be dried has the disadvantage
that the moist air being lighter than dry air distributes itself
in the upper portion of the desiccator and not below. Hempel,
in his desiccator (1891), avoids this by placing the absorbent
above the substance to be dried. The process of desiccation
can be further accelerated by cooling the upper portion of the
desiccator, and so inducing ascending and descending currents of
air within the apparatus.
From what has been said above, it is evident that the transference of
moisture to gases and the absorption of hygroscopic moisture present
great resemblance to, but still are not, chemical combinations with
water. Water, when combined as hygroscopic water, does not lose its
properties and does not form new substances.[15]
[15] Chappuis, however, determined that in wetting 1 gram of charcoal
with water 7 units of heat are evolved, and on pouring carbon
bisulphide over 1 gram of charcoal as much as 24 units of heat
are evolved. Alumina (1 gram), when moistened with water, evolves
2-1/2 calories. This indicates that in respect to evolution of
heat moistening already presents a transition towards exothermal
combinations (those evolving heat in their formation).
The attraction of water for substances which dissolve in it is of a
different character. In the solution of substances in water there
proceeds a peculiar kind of indefinite combination; a new homogeneous
substance is formed from the two substances taken. But here also the
bond connecting the substances is very unstable. Water containing
different substances in solution boils at a temperature near to its
usual boiling point. From the solution of substances which are lighter
than water itself, there are obtained solutions of a less density than
water--as, for example, in the solution of alcohol in water; whilst a
heavier substance in dissolving in water gives it a higher specific
gravity. Thus salt water is heavier than fresh.[16]
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account