The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
It is well known that water dissolves many substances. Salt, sugar,
alcohol, and a number of other substances, dissolve in water and form
homogeneous liquids with it. To demonstrate the solubility of gases
in water, a gas should be taken which has a high co-efficient of
solubility--for instance, ammonia. This is introduced into a bell jar
(or cylinder, as in fig. 14), which is previously filled with mercury
and stands in a mercury bath. If water be then introduced into the
cylinder, the mercury will rise, owing to the water dissolving the
ammonia gas. If the column of mercury be less than the barometric
column, and if there be sufficient water to dissolve the gas, all the
ammonia will be absorbed by the water. The water is introduced into
the cylinder by a glass pipette, with a bent end. The bent end is put
into water, and the air is sucked out from the upper end. When full of
water, its upper end is closed with the finger, and the bent end placed
in the mercury bath under the orifice of the cylinder. On blowing into
the pipette the water will rise to the surface of the mercury in the
cylinder owing to its lightness. The solubility of a gas like ammonia
may be demonstrated by taking a flask full of the gas, and closed
by a cork with a tube passing through it. On placing the tube under
water, the water will rise into the flask (this may be accelerated by
previously warming the flask), and begin to play like a fountain inside
it. Both the rising of the mercury and the fountain clearly show the
considerable affinity of water for ammonia gas, and the force acting
in this dissolution is rendered evident. A certain period of time is
required both for the homogeneous intermixture of gases (diffusion) and
the process of solution, which depends, not only on the surface of the
participating substances, but also on their nature. This is seen from
experiment. Solutions of different substances heavier than water, such
as salt or sugar, are poured into tall jars. Pure water is then very
carefully poured into these jars (through a funnel) on to the top of the
solutions, so as not to disturb the lower stratum, and the jars are then
left undisturbed. The line of demarcation between the solution and the
pure water will be visible, owing to their different co-efficients of
refraction. Notwithstanding that the solutions taken are heavier than
water, after some time complete intermixture will ensue. Gay Lussac
convinced himself of this fact by this particular experiment, which
he conducted in the cellars under the Paris Astronomical Observatory.
These cellars are well known as the locality where numerous interesting
researches have been conducted, because, owing to their depth under
ground, they have a uniform temperature during the whole year; the
temperature does not change during the day, and this was indispensable
for the experiments on the diffusion of solutions, in order that no
doubt as to the results should arise from a daily change of temperature
Public-domain text, read in full here on John Shaqi.
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