The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[16] Strong acetic acid (C_{2}H_{4}O_{2}), whose specific gravity at
15° is 1·055, does not become lighter on the addition of water
(a lighter substance, sp. gr. = 0·999), but heavier, so that a
solution of 80 parts of acetic acid and 20 parts of water has a
specific gravity of 1·074, and even a solution of equal parts of
acetic acid and water (50 p.c.) has a sp. gr. of 1·065, which is
still greater than that of acetic acid itself. This shows the
high degree of contraction which takes place on solution. In
fact, solutions--and, in general, liquids--on mixing with water,
decrease in volume.
We will consider _aqueous solutions_ somewhat fully, because, among
other reasons, solutions are constantly being formed on the earth and
in the waters of the earth, in plants and in animals, in chemical
processes and in the arts, and these solutions play an important part
in the chemical transformations which are everywhere taking place,
not only because water is everywhere met with, but chiefly because a
substance in solution presents the most favourable conditions for the
process of chemical changes, which require a mobility of parts and a
possible distension of parts. In dissolving, a solid substance acquires
a mobility of parts, and a gas loses its elasticity, and therefore
reactions often take place in solutions which do not proceed in the
undissolved substances. Further, a substance, distributed in water,
evidently breaks up--that is, becomes more like a gas and acquires a
greater mobility of parts. All these considerations require that in
describing the properties of substances, particular attention should be
paid to their relation to water as a solvent.
[Illustration: FIG. 14.--Method of transferring a gas into a cylinder
filled with mercury and whose open end is immersed under the mercury
in a bath having two glass sides. The apparatus containing the gas is
represented on the right. Its upper extremity is furnished with a tube
extending under the cylinder. The lower part of the vessel communicates
with a vertical tube. If mercury be poured into this tube, the pressure
of the gas in the apparatus is increased, and it passes through the
gas-conducting tube into the cylinder, where it displaces the mercury,
and can be measured or subjected to the action of absorbing agents, such
as water.]
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