The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
at a high temperature, and therefore if it dissolves an oxide, it may be
partially driven off from such a solution by prolonged and powerful
ignition; in which case the oxides previously in solution separate out in
a crystalline form, and frequently in the same forms as those in which
they occur in nature--for example, crystals of alumina, which by itself
fuses with difficulty, have been obtained in this manner. It dissolves in
molten boric anhydride, and separates out in natural rhombohedric
crystals. In this way Ebelmann also obtained _spinel_--that is, a
compound of magnesium and aluminium oxides which occurs in nature.[9]
[5] Metals, like Na, K, Li, give salts of the type of borax, MBO_{2} or
MH_{2}BO_{3}. A solution of borax, Na_{2}B_{4}O_{7}, has an
alkaline reaction, decomposes ammonia salts with the liberation of
ammonia (Bolley), absorbs carbonic anhydride like an alkali,
dissolves iodine like an alkali (Georgiewics), and seems to be
decomposed by water. Thus Rose showed that strong solutions of
borax give a precipitate of silver borate with silver nitrate,
whilst dilute solutions precipitate silver oxide, like an alkali.
Georgiewics even supposes (1888) boric anhydride to be entirely
void of acid properties; for all acids, on acting on a mixture of
solutions of potassium iodide and iodate, evolve iodine, but boric
acid does not do this. With dilute solutions of sodium hydroxide
Berthelot obtained a development of heat equal to 11-1/2 thousand
calories per equivalent of alkali (40 grams sodium hydroxide) when
the ratio Na_{2}O : 2B_{2}O_{3} (as in borax) was taken, and only 4
thousand calories when the ratio was Na_{2}O : B_{2}O_{3}, whence
he concludes that water powerfully decomposes those sodium borates
in which there is more alkali than in borax. Laurent (1849)
obtained a sodium compound, Na_{2}O,4B_{2}O_{3},10H_{2}O,
containing twice as much boric anhydride as borax, by boiling a
mixture of borax with an equivalent quantity of sal-ammoniac until
the evolution of ammonia entirely ceased.
Hence it is evident that feeble acids are as prone to, and as
easily, form acid salts (that is, salts containing much acid oxide)
as feeble bases are to give basic salts. These relations become
still clearer on an acquaintance with such feeble acids as silicic,
molybdic, &c. This variety of the proportions in which bases are
able to form salts recalls exactly the variety of the proportions
in which water combines with crystallo-hydrates. But the want of
sufficient data in the study of these relations does not yet permit
of their being generalised under any common laws.
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