The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Amorphous boron, like charcoal, dissolves in certain molten metals. The
property of fused _aluminium of dissolving boron_ in considerable
quantity is very striking; on cooling such a solution, the boron
partially combined with the aluminium separates out in a crystalline
form, and its properties are then exceedingly remarkable. The crystalline
boron may be obtained by heating (to 1,300°) the pulverulent boron with
aluminium in a well-closed crucible, the access of air being prevented as
far as possible. After cooling, crystals are observed on the surface of
the aluminium, and may easily be separated by dissolving the latter in
hydrochloric acid, which does not act on the crystals. The specific
gravity of the crystals is 2·68; they are partially transparent, but are
for the most part coloured dark brown; they contain about 4 p.c. of
carbon and up to 7 p.c. of aluminium, so that they cannot be considered
as pure boron. Nevertheless, the properties of this _crystalline_
substance, which was obtained by Wöhler and Deville, are very remarkable.
It most closely resembles _the diamond in its properties_--in fact, these
crystals have the lustre and high refracting power proper to the diamond
only, whilst their hardness competes with that of the diamond. Their
powder polishes even the diamond, and like the diamond scratches the
sapphire and corundum. Crystalline boron is much more stable with respect
to chemical reagents than the amorphous variety, and as it resembles the
diamond, so amorphous boron, on the other hand, distinctly recalls
certain of the properties of charcoal; thus a certain resemblance exists
between boron and carbon in a free state, which is further justified by
the proximity of their positions in the periodic system.
Among the other compounds of boron, those with nitrogen and the halogens
are the most remarkable. As already mentioned above, amorphous boron
combines directly with _nitrogen_ at a red heat. If it be heated in a
glass tube in a stream of nitric oxide, perfect combustion takes place,
5B + 3NO = B_{2}O_{3} + 3BN. If the residue be treated with nitric acid,
the boric anhydride dissolves, whilst the _boron nitride_ remains[11] as
an extremely light white powder, which is sometimes partially crystalline
and greasy to the touch, like talc. It is infusible and unchanged, even
at the melting-point of nickel. In general, it is remarkable for its
great stability with respect to chemical reagents. Nitric and
hydrochloric acids, as well as alkaline solutions, and hydrogen and
chlorine at a red heat, have no action on it. When fused with potash, it
evolves ammonia, and when ignited in steam it also yields ammonia: 2BN +
3H_{2}O = B_{2}O_{3} + 2NH_{3}.[12]
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