The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[10] _Amorphous boron_ is prepared by mixing 100 parts of powdered
boric anhydride with 50 parts of sodium in small lumps; this
mixture is thrown into a powerfully heated cast-iron crucible,
covered with a layer of ignited salt, and the crucible covered.
Reaction proceeds rapidly; the mass is stirred with an iron rod,
and poured directly into water containing hydrochloric acid. The
action is naturally accompanied by the formation of sodium borate,
which is dissolved, together with the salt, by the water, whilst
the boron settles at the bottom of the vessel as an insoluble
powder. It is washed in water, and dried at the ordinary
temperature. Magnesium, and even charcoal and phosphorus, are also
able to reduce boron from its oxide. Boron, in the form of an
amorphous powder, very easily passes through filter-paper, remains
suspended in water, and colours it brown, so that it appears to be
soluble in water. Sulphur precipitated from solutions shows the
same (colloidal) property. When borax is fused with magnesium
powder, it gives a brown powder of a compound of boron and
magnesium, Mg_{2}B (Winkler, 1890), but when a mixture of 1 part
of magnesium and 3 parts of B_{2}O_{3} is heated to redness
(Moissan, 1892), it forms amorphous boron in the form of a
chestnut-coloured powder, which, after being washed with water,
hydrochloric and hydrofluoric acids, is fused again with
B_{2}O_{3} in an atmosphere of hydrogen in order to prevent the
access of the nitrogen of the air, which is easily absorbed by
incandescent amorphous boron.
Sabatier (1891) considers that a certain amount of gaseous hydride
of boron is evolved in the action of hydrochloric acid upon the
alloys of magnesium and boron, because the gas disengaged burns
with a green flame. Still, the existence of hydride of boron
cannot be regarded as certain.
Under the action of the heat of the electric furnace boron forms
with carbon a _carbide_, BC, as Mühlhäuser and Moissan showed in
1893.
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