The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
By treating clay with strong sulphuric acid, which dissolves the alumina
in it, and then (by means of an alkaline carbonate) dissolving the silica
which was combined with the alumina in the clay (but not that occurring
in the form of sand, &c., which is hardly dissolved by carbonate of soda
solution at all even on boiling), we may form an idea of the proportion
between the component parts of a clay; and by igniting it at a high
temperature, we may determine the amount of water held in it. In the
purer sorts of clay dried at 100° (sp. gr. of pure kaolin is about 2·5)
this proportion is about 2SiO_{2} : 2H_{2}O : Al_{2}O_{3}. In this case
the conversion of felspar into kaolin is expressed by the equation:--
K_{2}O,Al_{2}O_{3},6SiO_{2} = Al_{2}O_{3},2SiO_{2} + K_{2}O,4SiO_{2};
Felspar Kaolin
the compound K_{2}O,4SiO_{2} passes into solution.
But as a rule clays contain from 45 to 60 p.c. of silica, from 20 to 30
p.c. of alumina, and about 12 p.c. of water; and it cannot be supposed
that clays are always homogeneous, because they are an aggregation of
residues (of silico-aluminous compounds) which are unacted on by water.
Nevertheless, clays always contain a hydrous compound of alumina and
silica, which is able to give up the alumina contained by it as a base to
strong sulphuric acid, forming aluminium sulphate, which is soluble in
water. After this treatment the silica remains, and is soluble in a
solution of an alkaline carbonate.[18]
[18] Everyone knows that a mixture of clay and water is endowed with
the property of taking a given form when subjected to a moderate
pressure. This plasticity of clay renders it an invaluable
material for practical purposes. From clay are moulded and
manufactured a variety of objects, beginning with the common brick
and ending with the most delicate china works of art. This
_plasticity of clay_ increases with its purity. When articles made
of clay are dried, the well-known hard mass is obtained; but water
washes it away, and furthermore, the cohesion of its particles is
not sufficiently great for it to resist the impression of blows,
shocks, &c. If such an article be subjected to the action of heat,
its volume first decreases, then it begins to lose water, and it
shrinks still further (in the case of a compact mass approximately
by 1/5 of its linear measurement). On the other hand, a great
coherence of particles is obtained, and thus burnt clay has the
hardness of stone. Pure clay, however, shrinks so considerably
when burnt that the form given to it is destroyed and cracks
easily form; such vessels are also porous, so that they will not
hold water. The addition of sand--that is, silica in fine
particles--or of _chamotte_--that is, already burnt and crushed
clay--renders the mass much more dense and incapable of cracking
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