The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
in the furnace. Nevertheless, such clay articles (bricks,
earthenware vessels, &c.) are still porous to liquids after being
burnt, because the clay in the furnace is only baked and does not
fuse. In order to obtain articles impervious to water the clay
must either be mixed with substances which form a glassy mass in
the furnace, permeating the clay and filling up its pores, or else
only the surface of the article is covered with such a glassy
fusible substance. In the first case the purest kinds of clay give
what is known as china, in the second case porcelain or 'faïence.'
So, for instance, by covering the surface of clay articles with a
layer of the oxides of lead and tin, the well-known white glaze is
obtained, because the oxides of these metals give a white gloss
when fused with silica and clay. In the preparation of china,
fluor spar and finely ground silica is mixed up into the clay;
these ingredients give a mass which is infusible but softens in
the furnace, so that all the particles of the clay cohere in this
softened mass, which hardens on cooling. A glaze composed of
glassy substances, which only fuse at a high temperature, is also
applied to the surface of china articles.
Clay is the source from which alumina, Al_{2}O_{3}, and the majority of
the compounds of aluminium are prepared. Among these compounds the most
important are the alums--that is, the double sulphates of potassium (and
allied metals) and aluminium, AlK(SO_{4})_{2},12H_{2}O. When clay is
treated with sulphuric acid diluted with a certain amount of water,
aluminium sulphate, Al_{2}(SO_{4})_{3}, is formed; and if potassium
carbonate or sulphate be added to this solution, a double salt or alum is
obtained in solution. The alums crystallise easily, and are prepared on a
very large manufacturing scale owing to their being employed in the
process of dyeing. Alums are soluble in water, and, on the addition of
ammonia to their solutions, they give _hydrous alumina_, or _aluminium
hydroxide_, as a white gelatinous precipitate, which is insoluble in
water but easily soluble in acids, even when dilute, and in aqueous soda
or potash. The solubility of alumina in acids indicates the basic
character of the oxide, and its solubility in alkalis and its power of
forming compounds with them shows the weakness of this basic character.
However, the feeblest acids, even carbonic acid, take up the alkali from
such a solution, and the alumina then separates out in a precipitate as
the hydroxide. It must also be remembered as characteristic of the
salt-forming properties of alumina that it does not combine with such
feeble acids as carbonic, sulphurous, or hypochlorous, &c.--that is, its
compounds with these acids are decomposed by water. It is also important
to observe that the hydroxide is not soluble in aqueous ammonia.
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