The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[38] Aluminium, when heated to the high temperature of the electric
furnace, dissolves carbon and forms an alloy which, according to
Moissan, when rapidly treated with _cold_ hydrochloric acid leaves
a compound C_{3}Al_{4} in the form of a yellow crystalline
transparent powder, sp. gr. 2·36 (_see_ Chapter VIII. Note 12
bis). This _carbide of aluminium_ C_{3}Al_{4} corresponds to
methane CH_{4}, for Al replaces H_{3} and carbon O_{2} or H_{4},
that is, it is equal to three molecules of CH_{4} with the
substitution of twelve atoms of H in it by four of Al, or, what is
the same thing, it is the duplicated molecule of Al_{2}O_{3} with
the substitution of O_{6} by C_{3}. And indeed C_{3}Al_{4} under
the action of water forms marsh gas and hydrate of alumina:
C_{3}Al_{4} + 12H_{2}O = 3CH_{4} + 4Al(OH)_{3}. This decomposition
gives a new aspect of the synthesis of hydrocarbons, and quite
agrees with what should follow from the action of water upon the
metallic carbides as applied by me for explaining the origin of
naphtha (Chapter VIII., Notes 57, 58, and 59). Frank (1894) by
heating Al with carbon obtained a similar although not quite pure
compound, which (like CaC_{2}) evolves acetylene with hydrochloric
acid _i.e._ probably has the composition AlC_{3}.
Aluminium forms alloys with different metals with great ease. Among them
the copper alloy is of practical use. It is called _aluminium bronze_.
This alloy is prepared by dissolving 11 p.c. by weight of metallic
aluminium in molten copper at a white heat. The formation of the alloy is
accompanied by the development of a considerable quantity of heat, so
that it glows to a bright white heat. This alloy, which corresponds with
the formula AlCu_{3}, presents an exceedingly homogeneous mass,
especially if perfectly pure copper be taken. It is distinguished for its
capacity to fill up the most minute impressions of the mould into which
it may be cast, and by its extraordinary elasticity and toughness, so
that objects cast from it may be hammered, drawn, &c., and at the same
time it is fine-grained and exceedingly hard, takes an excellent polish,
and, what is most important, its surface then remains almost unchangeable
in the air, and has a colour and lustre which may be compared to that of
gold alloys. Hence aluminium bronze is much used in the arts for making
spoons, watches, vessels, forks, knives, and for ornaments, &c. No less
important is the fact that the admixture of one-thousandth part of
aluminium with steel renders its castings homogeneous (free from
cavities) to an extent that could not be arrived at by other means, nor
does the quality of the steel in any respect deteriorate by this
admixture, but rather is it improved. In a pure state, aluminium is only
employed for such objects as require the hardness of metals with
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