The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
comparative lightness, such as telescopes and various physical apparatus
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According to the periodic system of the elements, the analogues of
magnesium are zinc, cadmium, and mercury in the second group. So also in
the third group, to which aluminium belongs, we find its corresponding
analogues _gallium_, _indium_, and _thallium_. They are all three so
rarely and sparingly met with in nature that they could only be
discovered by means of the spectroscope. This fact shows that they are
partially volatile, as should be the case according to the property of
their nearest neighbours, the very volatile zinc, cadmium and mercury. As
with them, in gallium, indium, and thallium the density of the metal,
decomposability of compounds, &c., rises with the atomic weight. But here
we find a peculiarity which does not exist in the second group. In the
latter, the fusibility increases with the atomic weight of magnesium,
zinc, cadmium, and mercury; indeed, the heaviest metal--mercury--is a
liquid. In the third group it is not so. In order to understand this it
is sufficient to turn our attention to the elements of the further groups
of the uneven series--for instance, to group V., containing phosphorus,
arsenic, and antimony, or to group VI., with sulphur, selenium, and
tellurium, and also to group VII., where chlorine, bromine and iodine are
situated. In all these instances the fusibility decreases with a rise of
atomic weight; the members of the higher series, the elements of a high
atomic weight, fuse with greater difficulty than the lighter elements.
The representatives of the uneven series of group III., aluminium,
gallium, indium, thallium, forming, as they do, a transition, all show an
intermediate behaviour. Here the most fusible of all is the medium metal
gallium,[38 bis] which fuses at the heat of the hand; whilst indium,
thallium, and aluminium fuse at much higher temperatures.
[38 bis] The same is the case in group IV. of the uneven series, where
tin is the most fusible. Thus the temperature of fusion rises on
both sides of tin (silicon is very infusible; germanium, 900°;
tin, 230°; lead, 326°); as it also does in group III., starting
from gallium, for indium fuses at 176°, less easily than gallium
but more easily than thallium (294°). Aluminium also fuses with
greater difficulty than gallium.
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