The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
applicability of the periodic system of the elements. It must be remarked
that previous to it there was no means of either foretelling the
properties or even the existence of undiscovered elements.[39]
[39] The spectrum of gallium is characterised by a brilliant violet
line of wave-length = 417 millionths of a millimetre. The metal
can be separated from the solution, containing a mixture of the
many metals occurring in the zinc blende, by making use of the
following reactions: it is precipitated by sodium carbonate in the
first portions; it gives a sulphate which, on boiling, easily
decomposes into a basic salt, very slightly soluble in water; and
it is deposited in a metallic state from its solutions by the
action of a galvanic current. It fuses at +30°, and, when once
fused, remains liquid for some time. It oxidises with difficulty,
evolves hydrogen from hydrochloric acid and from potassium
hydroxide, and, like all feeble bases (for instance, alumina and
indium oxide), it easily forms basic salts. The hydroxide is
soluble in a solution of caustic potash, and slightly so in
caustic ammonia. Gallium forms volatile GaCl_{3} and GaCl_{2}
(Nilson and Pettersson).
Much more light has been thrown on that element of the aluminium group
which follows after cadmium (its position in the periodic system is III.,
7, that is, it is in group III. in the 7th series). This is _indium_, In,
which also occurs in small quantities in certain zinc ores. It was
discovered (1863) by Reich and Richter (and more fully investigated by
Winkler) in the Freiberg zinc ores, and was named indium from the fact
that it gives to the flame of a gas-burner a blue coloration, owing to
the indigo blue spectral lines proper to it. The equivalent (_see_
Chapter XV., Note 15), specific heat, and other properties of the metal
confirm the atomic weight In = 113.[40]
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