The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Zinc (group II.), which has an atomic weight 65, should be followed in
group III. by an element with an atomic weight of about 69. It will be in
the same group as Al and should consequently give R_{2}O_{3}, RCl_{3},
R_{2}(SO_{4})_{3}, alums and similar compounds analogous to those of
aluminium. Its oxide should be more easily reducible to metal than
alumina, just as zinc oxide is more easily reduced than magnesia. The
oxide R_{2}O_{3} should, like alumina, have feeble but clearly expressed
basic properties. The metal reduced from its compounds should have a
greater atomic volume than zinc, because in the fifth series, proceeding
from zinc to bromine, the volume increases. And as the volume of zinc =
9·2, and of arsenic = 18, that of our metal should be near to 12. This is
also evident from the fact that the volume of aluminium = 11, and of
indium = 14, and our metal is situated in group III., between aluminium
and indium. If its volume = 11·5 and its atomic weight be about 69, then
its density will be nearly 5·9. The fact that zinc is more volatile than
magnesium gives reason for thinking that the metal in question will be
more volatile than aluminium, and therefore for expecting its discovery
by the aid of the spectroscope, &c.
These properties were indicated by me for the analogue of aluminium in
1871, and I named it (_see_ Chapter XV.) eka-aluminium. In 1875, Lecoq de
Boisbaudran, who had done much work in spectrum analysis, discovered a
new metal in a zinc blende from the Pyrenees (Pierrefitte). He recognised
its individuality and difference from zinc, cadmium, indium, and the
other companions of zinc by means of the spectroscope; but he only
obtained some fractions of a centigram of it in a free state.
Consequently only a few of its reactions were determined, as, for
instance, that barium carbonate precipitates the new oxide from its salts
(alumina, as is known, is also precipitated). Lecoq de Boisbaudran named
the newly discovered metal _gallium_. As one would expect the same
properties for eka-aluminium as were observed in gallium, I pointed out
this fact at the time in the Memoirs of the Paris Academy of Sciences.
All the subsequent observations of Lecoq de Boisbaudran confirmed the
identity between the properties of gallium and those indicated for
eka-aluminium. Immediately after this the ammonium alum of gallium was
obtained, but the most convincing proof of all was found in the fact that
the density of gallium although first apparently different (4·7) from
that indicated above, afterwards, when the metal was carefully purified
from sodium (which was first used as a reducing agent), proved to be just
that (5·9) which would have been looked for in the analogue of aluminium;
and, what was very important, the equivalent (23·3) and atomic weight
(69·8) determined by the specific heat (0·08) were shown by experiment to
be such as would be expected. These facts confirmed the universality and
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