The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
As regards the higher oxide or the _thallic oxide_, Tl_{2}O_{3},
the thallium is trivalent in it--that is, it forms compounds of
the type TlX_{3}. The hydroxide, TlO(OH), is formed by the action
of hydrogen peroxide on thallous oxide, or by the action of
ammonia on a solution of thallic chloride, TlCl_{3}. It is
obtained as a brown precipitate, insoluble in water but easily
soluble in acids, with which it gives thallic salts, TlX_{3}.
Thallic chloride, which is obtained by cautiously heating the
metal in a stream of chlorine, forms an easily fusible white mass,
which is soluble in water and able to part with two-thirds of its
chlorine when heated. An aqueous solution of this salt yields
colourless crystals containing one equivalent of water. It is
evident from the above that all the thallic salts can easily be
reduced to thallous salts by reducing agents such as sulphurous
anhydride, zinc, &c. Besides these salts, thallic sulphate,
Tl_{2}(SO_{4})_{3},7H_{2}O, thallic nitrate
Tl(NO_{3})_{3},4H_{2}O, &c., are known. These salts are decomposed
by water, like the salts of many feeble basic metals--for example,
aluminium.
Gallium, indium, and thallium belong to the uneven series, and there
should be elements of the even series in group III. corresponding with
calcium, strontium, and barium in group II. These elements should in
their oxides R_{2}O_{3} present basic characters of a more energetic kind
than those shown by alumina, just as calcium, strontium, and barium give
more energetic bases than magnesium, zinc, and cadmium. Such are
_yttrium_ and _ytterbium_, which occur in a rare Swedish mineral called
_gadolinite_, and are therefore termed the gadolinite metals. To these
belong also the metal _lanthanum_, which accompanies the two other metals
_cerium_ and _didymium_ in the mineral _cerite_, and it therefore belongs
to the cerite metals. All these metals and certain others accompanying
them, give basic oxides R_{2}O_{3}. At first their formula was supposed
to be RO, but the application of the periodic system required their being
counted as elements of groups III. and IV., which was also confirmed by
the determination of the specific heats of these metals,[42] and better
still by the fact that Nilson and Clève, in their researches on the
gadolinite metals (1879), discovered that they contain a peculiar and
very rare element, _scandium_, which by the magnitude of its atomic
weight, Sc = 44, and in all its properties, exactly corresponds with the
metal (previously foretold on the basis of the periodic system)
_ekaboron_, whose properties were determined by taking the cerite and
gadolinite metals as forming oxides R_{2}O_{3}.[43]
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account