The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[42] The specific heat of cerium determined (1870) by me, and
afterwards confirmed by Hillebrand, corresponds with that atomic
weight of cerium according to which the composition of two oxides
should be Ce_{2}O_{3} and CeO_{2}. Hillebrand also obtained
metallic lanthanum and didymium by decomposing their salts by a
galvanic current, and he found their specific heats to be near
that of cerium and about 0·04, and it is therefore justifiable to
give them an atomic weight near that of cerium, as was done on the
basis of the periodic law. Up to 1870 yttrium oxide was also given
the formula RO. Having re-determined the equivalent of yttrium
oxide (with respect to water), and found it to be 74·6, I
considered it necessary to also ascribe to it the composition
Y_{2}O_{3}, because then it falls into its proper place in the
periodic system. If the equivalent of the oxide to water be 74·6,
it contains 58·6 of metal per 16 of oxygen, and consequently one
part by weight of hydrogen replaces 29·3 of yttrium, and if it be
regarded as bivalent (oxide RO), it would not, by its atomic
weight 58·6, find a place in the second group. But if it be taken
as trivalent--that is, if the formula of its oxide be R_{2}O_{3}
and salts RX_{3}--then Y = 88, and a position is open for it in
the third group in the sixth series after rubidium and strontium.
These alterations in the atomic weights of the cerite and
gadolinite metals were afterwards accepted by Clève and other
investigators, who now ascribe a formula R_{2}O_{3} to all the
newly discovered oxides of these metals. But still the position in
the periodic system of certain elements--for example of holmium,
thulium, samarium, and others--has not yet been determined for
want of a sufficient knowledge of their properties in a state of
purity.
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