The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
The cerite and gadolinite metals occur in rare siliceous minerals
from Sweden, America, the Urals, and Baikal, such as cerite (in
Sweden), gadolinite, and orthite; and in still rarer minerals
formed by titanic, niobic, and tantalic acids, such as euxenite in
Norway and America, and samarskite in Norway, the Urals and
America, and in a few rare fluorides and phosphates. Among the
latter, monazite is found in somewhat considerable quantities in
Brazil and North Carolina; this contains the phosphate of cerium,
CePO_{4} (= Ce_{2}O_{3}P_{2}O_{3}), together with didymium,
thorium and lanthanum (according to W. Edron and Shapleigh's
analyses), and is now used for preparing that mixture of the
oxides of the rare metals (especially ThO_{2}, Ce_{2}O_{3},
La_{2}O_{3}, &c.), which is employed for incandescent burners
(Auer von Welsbach), as it has been found by experiment that these
oxides when raised to incandescence in a non-luminous gas flame,
give a far more brilliant flame with a smaller consumption of gas,
besides being suitable for such non-luminous gases as water gas.
The insufficiency of material to work upon, and the difficulty of
separating the oxides from each other, are the chief reasons why
the composition of the compounds of these rare metals is so
imperfectly known. Cerite is the most accessible of these
minerals. Besides silica it contains more than 50 p.c. of the
oxides of cerium, lanthanum (from 4 p.c.), and didymium. The
decomposition of its powder by sulphuric acid gives sulphates, all
of which are soluble in water. The other minerals mentioned above
are also decomposed in the same manner. The solution of sulphates
is precipitated with free oxalic acid, which forms salts insoluble
in water and dilute acids with all the cerite and gadolinite
oxides. The oxides themselves are obtained by igniting the
oxalates. When ignited in the air the cerium passes from its
ordinary oxide Ce_{2}O_{3} into the higher oxide CeO_{2}, which is
so feeble a base that its salts are decomposed by water, and it is
insoluble in dilute nitric acid. Therefore it is always possible
to remove all the cerium oxide by repeated ignitions and solutions
in sulphuric acid. The further separation of the metals is mainly
based on four methods employed by many investigators.
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