The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[43] So, for example, in 1871, in the _Journal of the Russian
Physico-Chemical Society_ (p. 45) and in Liebig's _Annalen_, Supt.
Band viii. 198, I deduced, on the basis of the periodic law, an
atomic weight 44 for ekaboron, and Nilson in 1888 found that of
scandium, which is ekaboron, to be Sc = 44·03, The periodic law
showed that the specific gravity of the ekaboron oxide would be
about 8·5, that it would have decided but feeble basic properties
and that it would give colourless salts. And this proved to be the
case with scandium oxide. In describing scandium, Clève and Nilson
acknowledge that the particular interest attached to this element
is due to its complete identity with the expected element
ekaboron. And this accurate foretelling of properties could only
be arrived at by admitting that alteration of the atomic weights
of the cerite and gadolinite metals which was one of the first
results of the application of the periodic system of the elements
to the interpretation of chemical facts. In my first memoirs,
namely, in the _Bulletin of the St. Petersburg Academy of
Sciences_, vol. viii. (1870), and in Liebig's _Annalen_ (_l. c._
p. 168) and others, I particularly insisted on the necessity of
altering the then accepted atomic weights of cerium, lanthanum,
and didymium. Clève, Höglund, Hillebrand and Norton, and more
especially Brauner, and others accepted the proposed alteration,
and gave fresh proofs in favour of the proposed alterations of
these atomic weights. The study of the fluorides was particularly
important. Placing cerium in the fourth group, the composition of
its highest oxide would then be CeO_{2}, and its compounds CeX_{4}
and the lower oxide, Ce_{2}O_{3} or CeX_{3}. Brauner obtained the
fluoride CeF_{4},H_{2}O corresponding with the first, and a double
crystalline salt, 3KF,2CeF_{4},2H_{2}O, without any admixture of
compound of the lower grade CeX_{3}, which generally occur
together with the majority of salts corresponding with CeX_{4}. It
will be seen from these formulæ and from the tables of the
elements, that cerium and didymium do not belong to the third
group, which is now being described, but we mention them here for
convenience, as all the cerite and gadolinite metals have much in
common. These metals, which are rare in nature, resemble each
other in many respects, always accompany each other, are with
difficulty isolated from each other, and stand together in the
periodic system of the elements; they have acquired a peculiar
interest owing to their having been in 1870 the objects of the
study of Marignac, Delafontaine, Soret, Lecoq de Boisbaudran,
Brauner, Clève, Nilson, the professors of Upsala, and others.
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