The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
the elements, but as spectra vary with the temperature and
elasticity (concentration) this method cannot be considered as
trustworthy.
^d The most important point of distinction of individual metallic
oxides is given by the direct _determination of their equivalent
with respect to water_--that is, the amount of the oxide by weight
which combines (like water) with 80 parts by weight of sulphuric
anhydride, SO_{3}, for the formation of a normal salt. For this
purpose the oxide is weighed and dissolved in nitric acid,
sulphuric acid is then added, and the whole is evaporated to
dryness over a water-bath and then heated over a naked flame
sufficiently strongly to drive off the excess of sulphuric acid,
but so as not to decompose the salt (the product would in that
case not be perfectly soluble in water); then, knowing the weight
of the oxide and of the anhydrous sulphate, we can find the
equivalent of the oxide. The following are the most trustworthy
figures in this connection: scandium oxide 45·35 (Nilson), yttrium
oxide 75·7 (Clève; according to my determination, 1871--74·6),
cerous oxide--that is, the lower form of oxidation of cerium,
according to various investigators (Bunsen, Brauner, and others)
from 108 to 111, the higher oxide of cerium from 85 to 87,
lanthanum oxide, according to Brauner, 108, didymium oxide (in
salts of the ordinary lower form of oxidation) about 112
(Marignac, Brauner, Clève), samarium oxide about 116 (Clève),
ytterbium oxide 131·3 (Nilson). It may not be superfluous here to
draw attention to the fact that the equivalent of the oxides of
all the gadolinite and cerite metals for water distribute
themselves into four groups with a somewhat constant difference of
nearly 30. In the first group is scandium oxide with equivalent
45, in the second, yttrium oxide 76, in the third, lanthanum,
cerium, didymium, and samarium oxides with equivalent about 110,
and, in the fourth, erbium, ytterbium, and thorium oxides with
equivalent about 131. The common difference of period is nearly
45. And if we ascribe the type R_{2}O_{3} to all the oxides--that
is, if we triple the weight of the equivalent of the oxide--we
shall obtain a difference of the groups nearly equal to 90, which,
for two atoms of the metal, forms the ordinary periodic difference
of 45. If one and the same type of oxide R_{2}O_{3} be ascribed to
all these elements (as now generally accepted, in many cases there
being insufficiently trustworthy data), then the atomic weights
should be Sc = 44, Y = 89, La = 138, Ce = 140, Di = 144,
(neodymium 140, praseodymium 144), Sm = 150, Yb = 173, also
terbium 147, holmium 162, alphayttrium 157, erbium 166, thulium
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