The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
170, decipium 171. It should be observed that there may be
instances of basic salts. If, for example, an element with an
atomic weight 90 gave an oxide RO_{2}, but salts ROX_{2}, then by
counting its oxide as R_{2}O_{3} its atomic weight would be 159.
All the points distinguishing many gadolinite and cerite elements
have not been sufficiently well established in certain cases (for
example, with decipium, thulium, holmium, and others). At present
the most certain are yttrium, scandium, cerium, and lanthanum. In
the case of didymium, for example, there is still much that is
doubtful. Didymium, discovered in 1842 by Mosander after
lanthanum, differs from the latter in its absorption spectrum and
the lilac-rose colour of its salts. Delafontaine (1878) separated
samarium from it. Welsbach showed that it contains two particular
elements, neodymium (salts bluish-red) and praseodymium (salts
apple-green), and Becquerel (1887) by investigating the spectra of
crystals, recognised the presence of six individual elements.
Probably, therefore, many of the now recognised elements contain a
mixture of various others, and as yet there is not enough
confirmation of their individuality. As regards yttrium, scandium,
cerium, and lanthanum, which have been established without doubt,
I think that, owing to their great rarity in nature and chemical
art, it would be superfluous to describe them further in so
elementary a work as the present. We may add that Winkler (1891)
obtained a hydrogen compound of lanthanum, whose composition
(according to Brauner) is La_{2}H_{3}, as would be expected from
the composition of Na_{2}H, Mg_{2}H_{2}, &c. C. Winkler (1891), on
reducing CeO_{2} with magnesium, also remarked a rapid absorption
of hydrogen, and showed that a _hydride of cerium_, CeH_{2},
corresponding to CaH, and the other similar hydrides of metals of
the alkaline earths, is formed (Chapter XIV., Note 63).
The brevity of this work and the great rarity of the above-mentioned
elements will give me the right to exclude their description, all the
more as the principles of the periodic system enable many of their
properties to be foreseen, and as their practical uses (cerium oxalate is
used in medicine, and didymium oxide in the manufacture of glass, a
mixture of the oxides of lanthanum and similar metals is employed for
giving a bright light, as this mixture emits a brilliant white light when
brought to incandescence) are very limited, by reason of their great
rarity in nature, and the difficulty of separating them from one another.
CHAPTER XVIII
SILICON AND THE OTHER ELEMENTS OF THE FOURTH GROUP
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