The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[10] In reality, however, it would seem that the reaction is still more
complex, because the aqueous solution of silicon fluoride does not
yield a hydrate of silica, but a fluo-hydrate (Schiff),
Si_{2}O_{3}(OH)F, corresponding to the (pyro) hydrate
Si_{2}O_{3}(OH)_{2}, equal to SiO(OH)_{2}SiO_{2}, so that the
reaction of silicon fluoride on water is expressed by the
equation: 5SiF_{4} + 4H_{2}O = 3SiH_{2}F_{6} + Si_{2}O_{3}(OH)F +
HF. However, Berzelius states that the hydrate, when well washed
with water, contains no fluorine, which is probably due to the
fact that an excess of water decomposes Si_{2}O_{3}(OH)F, forming
hydrofluoric acid and the compound Si_{2}O_{3}(OH)_{2}. Water
saturated with silicon fluoride disengages silicon fluoride and
hydrofluoric acid when treated with hydrochloric acid, the
gelatinous precipitate being simultaneously dissolved. It may be
further remarked that hydrofluosilicic acid has been frequently
regarded as SiO_{2},6HF, because it is formed by the solution of
silica in hydrofluoric acid, but only two of these six hydrogens
are replaced by metals. On concentration, solutions of the acid
begin to decompose when they reach a strength of 6H_{2}O per
H_{2}SiF_{6}, and therefore the acid may be regarded as
Si(OH)_{4},2H_{2}O,6HF, but the corresponding salts contain less
water, and there are even anhydrous salts, R_{2}SiF_{6}, so that
the acid itself is most simply represented as H_{2}SiF_{6}.
If gaseous silicon fluoride be passed directly into water, the
gas-conducting tube becomes clogged with the precipitated silicic
acid. This is best prevented by immersing the end of the tube
under mercury, and then pouring water over the mercury; the
silicon fluoride then passes through the mercury, and only comes
into contact with the water at its surface, and consequently the
gas-conducting tube remains unobstructed. The silicic acid thus
obtained soon settles, and a colourless solution with a pleasant
but distinctly acid taste is procured.
Mackintosh, by taking 9 p.c. of hydrofluoric acid, observed that
in the course of an hour its action on opal attained 77 p.c. of
the possible, and did not exceed 1-1/2 p.c. of its possible action
on quartz during the same time. This shows the difference of the
structure of these two modifications of silica, which will be more
fully described in the sequel.
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