The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[11 bis] The following consideration is very important in explaining
the nature of the lower hydrates which are known for silicon. If
we suppose water to be taken up from the first hydrates (just as
formic acid is CH(OH)_{3}, _minus_ water), we shall obtain the
various lower hydrates corresponding with silicon hydride. When
ignited they should, like phosphorous and hypophosphorous acids,
disengage silicon hydride, and leave a residue of silica
behind--_i.e._ of the oxide corresponding to the highest
hydrate--just as organic hydrates (for example, formic acid with
an alkali) form carbonic anhydride as the highest oxygen compound.
Such imperfect hydrates of silicon, or, more correctly speaking,
of silicon hydride, were first obtained by Wöhler (1863) and
studied by Geuther (1865), and were named after their
characteristic colours. (_See_ Note 6).
_Leucone_ is a white hydrate of the composition SiH(OH)_{3}. It is
obtained by slowly passing the vapour of silicon chloroform into
cold water: SiHCl_{3} + 3H_{2}O = SiH(OH)_{3} + 3HCl. But this
hydrate, like the corresponding hydrate of phosphorus or carbon,
does not remain in this state of hydration, but loses a portion of
its water. The carbon hydrate of this nature, CH(OH)_{3}, loses
water and forms formic acid, CHO(OH); but the silicon hydrate
loses a still greater proportion of water, 2SiH(OH)_{3}, parting
with 3H_{2}O, and consequently leaving Si_{2}H_{2}O_{3}. This
substance must be an anhydride; all the hydrogen previously in the
form of hydroxyl has been disengaged, two remaining hydrogens
being left from SiH_{4}. The other similar hydrate is also white,
and has the composition Si_{3}H_{2}O (nearly). It may be regarded
as the above white hydrate + SiO_{2}. A yellow hydrate, known as
_chryseone_ (silicone), is obtained by the action of hydrochloric
acid on an alloy of silicon and calcium; its composition is about
Si_{6}H_{4}O_{3}. Most probably, however, chryseone has a more
complex composition, and stands in the same relation to the
hydrate SiH_{2}(OH)_{3} as leucone does to the hydrate
SiH(OH)_{3}, because this very simply expresses the transition of
the first compound into the second with the loss of water,
SiH_{2}(OH)_{3} - H_{2} + H_{2}O = SiH(OH)_{3}. When these lower
hydrates are ignited without access of air, they are decomposed
into hydrogen, silicon, and silica--that is, it may be supposed
that they form silicon hydride (which decomposes into silicon and
hydrogen) and silica (just as phosphorous and hypophosphorous
acids give phosphoric acid and phosphuretted hydrogen). When
ignited in air, they burn, forming silica. They are none of them
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