The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
acted on by acids, but when treated with alkalis they evolve
hydrogen and give silicates; for example, leucone: SiH_{2}O_{3} +
4KHO = 2SiK_{2}O_{3} + H_{2}O + 2H_{2}. They have no acid
properties.
Silica or silicic anhydride, both in the free state and in combination
with other oxides, enters into the composition of most of the rocky
formations of the earth's crust. These silicious compounds are substances
varying so much in their properties, crystalline forms, and relations to
one another that they are comprised in a special branch of natural
science (like the carbon compounds), and are treated of in works on
mineralogy; so that, in dealing with them further, we shall only give a
short description of these various compounds. It is first of all
necessary to turn to the description of silica itself, especially as it
is not unfrequently met with in nature in a separate state, and often
forms whole masses of rocky formations, called 'quartz.' In an anhydrous
condition silica appears in the greatest variety of natural
forms--sometimes in well-formed crystals, hexagonal prisms, terminated by
hexagonal pyramids. If the crystals are colourless and transparent, they
are called _rock crystal_. This is the purest form of silica. Prismatic
crystals of rock crystal sometimes attain considerable size, and as they
are remarkable for their unchangeability, great hardness, and high index
of refraction, they are used for ornaments, for seals, making necklaces,
&c.[12] Rock crystal coloured with organic matter in contact with which
it has been produced has a brown or greyish colour, and then bears the
name of _cairngorm_ or _smoky quartz_. In this form it has the same uses
as rock crystal, especially as it is often found in large masses. The
same mineral, frequently occurs, coloured red or pink by manganese or
iron oxides, especially in aqueous formations, and is then known as
_amethyst_. When finely coloured the amethyst is used as a precious
stone, but amethysts most frequently occur as small crystals in the
cavities formed in other rocky formations, and especially in those formed
in silica itself. A similar anhydrous silica is often found in
transparent non-crystalline masses, having the same specific gravity as
rock crystal itself (2·66). In this case it is called _quartz_. Sometimes
it forms complete rocky formations, but more often penetrates or is
interspersed through other rocky formations, together with other
siliceous compounds. Thus, in granite, quartz is mixed with felspar and
similar substances. Sometimes the colouring of quartz is so considerable
that it is hardly transparent in thin sheets, but it is often found in
transparent masses slightly coloured with various tints. The existence in
nature of enormous masses of quartz proves that it resists the action of
water. When water destroys rocky formations, the siliceous minerals which
they contain are partly dissolved and partly transformed into clay, &c.
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